[3S,5R]-6-(4-methoxy-benzyloxy)-3,5-dimethyl-hexanal

Base Information Edit

Chemical Name:[3S,5R]-6-(4-methoxy-benzyloxy)-3,5-dimethyl-hexanal
CAS No.:440104-13-2
Molecular Formula:C₁₆H₂₄O₃
Molecular Weight:264.365
Hs Code.:
Mol file:440104-13-2.mol

Synonyms:[3S,5R]-6-(4-methoxy-benzyloxy)-3,5-dimethyl-hexanal

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Chemical Property of [3S,5R]-6-(4-methoxy-benzyloxy)-3,5-dimethyl-hexanal Edit

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Technology Process of [3S,5R]-6-(4-methoxy-benzyloxy)-3,5-dimethyl-hexanal

There total 10 articles about [3S,5R]-6-(4-methoxy-benzyloxy)-3,5-dimethyl-hexanal which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

: 440104-12-1
[3S,5R]-6-(4-methoxy-benzyloxy)-3,5-dimethyl-hexanenitrile

: 440104-13-2
[3S,5R]-6-(4-methoxy-benzyloxy)-3,5-dimethyl-hexanal

Guidance literature:: With diisobutylaluminium hydride; In dichloromethane; toluene; at -78 ℃; for 4h;
DOI:10.1021/ol025872f

Reference yield:

: 440104-11-0
[2S,4R]-O-(4-toluene-sulfonate)-5-(4-methoxy-benzyloxy)-2,4-dimethyl-pentan-1-ol

: 440104-13-2
[3S,5R]-6-(4-methoxy-benzyloxy)-3,5-dimethyl-hexanal

Guidance literature:: Multi-step reaction with 2 steps

1: 95 percent / dimethylsulfoxide / 5 h / 85 °C

2: 84 percent / DIBAL-H / CH₂Cl₂; toluene / 4 h / -78 °C

With diisobutylaluminium hydride; In dichloromethane; dimethyl sulfoxide; toluene;
DOI:10.1021/ol025872f

Reference yield:

: 7586-22-3,71372-08-2,82917-27-9,85646-66-8,92999-34-3,96612-17-8,100227-53-0,100227-54-1,114884-21-8
methyl hydrogen meso-2,4-dimethylethylglutarate

: 440104-13-2
[3S,5R]-6-(4-methoxy-benzyloxy)-3,5-dimethyl-hexanal

Guidance literature:: Multi-step reaction with 10 steps

1.1: 95 percent / H₂SO₄ / benzene / 18 h / Heating

2.1: α-chymotrypsin; NaOH / aq. phosphate buffer / 90 h / 20 °C / pH 7.5 - 7.8

3.1: 99 percent / B(OMe)3; BH₃*DMS / tetrahydrofuran / 42 h / 20 °C

4.1: 86 percent / imidasole / dimethylformamide / 18 h / 20 °C

5.1: 96 percent / DIBAL-H / toluene; heptane / 2 h / -78 °C

6.1: sodium hydride / dimethylformamide; various solvent(s) / 0.5 h / 0 °C

6.2: 91 percent / Bu₄NI / dimethylformamide; various solvent(s) / 18 h / 20 °C

7.1: 96 percent / tetrabutylammonium fluoride / tetrahydrofuran / 18 h / 20 °C

8.1: 98 percent / 4-dimethylaminopyridine; triethylamine / CH₂Cl₂ / 18 h / 20 °C

9.1: 95 percent / dimethylsulfoxide / 5 h / 85 °C

10.1: 84 percent / DIBAL-H / CH₂Cl₂; toluene / 4 h / -78 °C

With 1H-imidazole; dmap; sodium hydroxide; Trimethyl borate; dimethylsulfide borane complex; sulfuric acid; tetrabutyl ammonium fluoride; sodium hydride; diisobutylaluminium hydride; triethylamine; α-chymotrypsin; In tetrahydrofuran; phosphate buffer; n-heptane; dichloromethane; dimethyl sulfoxide; N,N-dimethyl-formamide; toluene; benzene;
DOI:10.1021/ol025872f