4-methoxyphenyl (phenyl)iodonium phosphorus hexafluoride

Base Information

• Chemical Name: 4-methoxyphenyl (phenyl)iodonium phosphorus hexafluoride
• CAS No.: 80134-77-6
• Molecular Formula: C₁₃H₁₂IO*F₆P
• Molecular Weight: 456.106
• Mol file: 80134-77-6.mol

Synonyms:4-methoxyphenyl (phenyl)iodonium phosphorus hexafluoride

Chemical Property of 4-methoxyphenyl (phenyl)iodonium phosphorus hexafluoride

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 4-methoxyphenyl (phenyl)iodonium phosphorus hexafluoride

There total 3 articles about 4-methoxyphenyl (phenyl)iodonium phosphorus hexafluoride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

[bis(acetoxy)iodo]benzene (3240-34-4) + methoxybenzene (100-66-3) → 4-methoxyphenyl (phenyl)iodonium phosphorus hexafluoride (80134-77-6)

Guidance literature:

[bis(acetoxy)iodo]benzene; methoxybenzene; With toluene-4-sulfonic acid; In acetonitrile; at 20 ℃; for 2h; Inert atmosphere; Darkness;

With sodium hexaflorophosphate; In water; Darkness;

DOI:10.1016/j.jfluchem.2010.04.004

Reference yield: 77.9%

[bis(acetoxy)iodo]benzene (3240-34-4) + para-iodoanisole (696-62-8) → 4-methoxyphenyl (phenyl)iodonium phosphorus hexafluoride (80134-77-6)

Guidance literature:

[bis(acetoxy)iodo]benzene; para-iodoanisole; With toluene-4-sulfonic acid; In acetonitrile; at 20 ℃; for 2h;

With sodium hexaflorophosphate; In water;

DOI:10.1021/ol101154h

Reference yield: 77.9%

→ 4-methoxyphenyl (phenyl)iodonium phosphorus hexafluoride (80134-77-6)

Guidance literature:

upstream raw materials:

[bis(acetoxy)iodo]benzene

para-iodoanisole

methoxybenzene

Downstream raw materials:

fluorobenzene

1-fluoro-4-methoxybenzene

C₂H₃O₂^(1-)*C₁₃H₁₂IO⁽¹⁺⁾

iodobenzene

Refernces

• 1、 -. "FLUORINATION OF AROMATIC RING SYSTEMS". Page/Page column 40. . Retrieved 2010/05/13.
• 2、 Wang, Bijia,Cerny, Ronald L.,Uppaluri, Shriharsha,Kempinger, Jayson J.,Dimagno, Stephen G.. "Fluoride-promoted ligand exchange in diaryliodonium salts". experimental part. p. 1113 - 1121. Retrieved 2011/02/25.