2,3,7,8,12,13,17,18-OCTAETHYL-21H,23H-PORPHINE COBALT(II)

Base Information

• Chemical Name: 2,3,7,8,12,13,17,18-OCTAETHYL-21H,23H-PORPHINE COBALT(II)
• CAS No.: 17632-19-8
• Molecular Formula: C36H44 Co N4
• Molecular Weight: 591.765
• Mol file: 17632-19-8.mol

Synonyms:Cobalt,[2,3,7,8,12,13,17,18-octaethyl-21H,23H-porphinato(2-)-N21,N22,N23,N24]-,(SP-4-1)-; Cobalt, [2,3,7,8,12,13,17,18-octaethylporphinato(2-)]- (8CI);21H,23H-Porphine, 2,3,7,8,12,13,17,18-octaethyl-, cobalt complex;21H,23H-Porphine, cobalt deriv.;(2,3,7,8,12,13,17,18-Octaethylporphinato)cobalt; (2,3,7,8,12,13,17,18-Octaethylporphyrinato)cobalt;2,3,7,8,12,13,17,18-Octaethyl porphine cobalt(II);2,3,7,8,12,13,17,18-Octaethyl-21H,23H-porphinecobalt(II); Cobalt2,3,7,8,12,13,17,18-octaethyl-21H,23H-porphyrin; Cobalt octaethylporphine;Cobalt octaethylporphyrin; Cobalt(2+) octaethylporphyrin; Cobalt(II)octaethylporphyrin; Cobaltous octaethylporphyrin;Octaethylporphinatocobalt(II); Octaethylporphyrincobalt

Chemical Property of 2,3,7,8,12,13,17,18-OCTAETHYL-21H,23H-PORPHINE COBALT(II)

Chemical Property:

• PSA: 34.58000
• LogP: 6.13420

Purity/Quality:

98%,99%, ^*data from raw suppliers

2,3,7,8,12,13,17,18-Octaethyl-21H,23H-porphine cobalt(II) ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

Technology Process of 2,3,7,8,12,13,17,18-OCTAETHYL-21H,23H-PORPHINE COBALT(II)

There total 15 articles about 2,3,7,8,12,13,17,18-OCTAETHYL-21H,23H-PORPHINE COBALT(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

dicobalt octacarbonyl (15226-74-1,61091-28-9,61117-58-6) + 2,3,7,8,12,13,17,18-octaethyl-porphyrin (2683-82-1,106117-28-6,991-75-3) → 2,3,7,8,12,13,17,18-octaethyl-21H,23H-porphine cobalt(II) (17632-19-8)

Guidance literature:

With aluminum oxide; lithium hydroxide; for 0.583333h; Time; Reagent/catalyst; Milling; Green chemistry;

DOI:10.1039/d0gc01010c

Reference yield: 87.0%

cobalt(II) acetate (71-48-7,917-69-1,5931-89-5,55881-15-7,68931-68-0,68931-69-1,93029-27-7) + 2,3,7,8,12,13,17,18-octaethyl-porphyrin (2683-82-1,106117-28-6,991-75-3) → 2,3,7,8,12,13,17,18-octaethyl-21H,23H-porphine cobalt(II) (17632-19-8)

Guidance literature:

In methanol; chloroform; for 0.5h; Reflux;

DOI:10.1134/S1070363220100102

Reference yield:

2,3,7,8,12,13,17,18-octaethylporphyrin (106117-28-6,991-75-3) + cobalt(II) chloride (7646-79-9,14543-09-0,16413-89-1) → 2,3,7,8,12,13,17,18-octaethyl-21H,23H-porphine cobalt(II) (17632-19-8)

Guidance literature:

In ethanol; for 0.05h; Sealed tube; Microwave irradiation;

DOI:10.1016/j.jconrel.2018.09.027

upstream raw materials:

2,3,7,8,12,13,17,18-octaethylporphyrin

cobalt(II) acetate

cobalt(II) diacetate tetrahydrate

octaethyl(CH{CCCNC})4(C(COOCH₃)COOCH₃)cobalt(III)Br

Downstream raw materials:

{Co(III)(octaethylporphyrin)}radical⁽²⁺⁾(Br)2

octaethylporphyrinato cobalt(II) bromide

{Co(III)(octaethylporphyrin)}radical⁽²⁺⁾(ClO₄)2

Co(octaethylporphyrin)(piperidine)

Refernces

• 1、 Asher, Sanford A.,Murtaugh, James. "Metalloporphyrin Gas and Condenced-Phase Resonance Raman Studies: The Role of Vibrational Anharmonicities as Determinants of Raman Frequencies". . p. 7244 - 7251. Retrieved 1983.
• 2、 Kadish, Karl M.,Adamian, Victor A.,Van Caemelbecke, Eric,Gueletii, Elena,Will, Stefan,Erben, Christoph,Vogel, Emanuel. "Electrogeneration of oxidized corrole dimers. Electrochemistry of (OEC)M where M = Mn, Co, Ni, or Cu and OEC is the trianion of 2,3,7,8,12,13,17,18- octaethylcorrole". . p. 11986 - 11993. Retrieved 1998.
• 3、 Fujita, Etsuko,Chang, C. K.,Fajer, Jack. "Cobalt(II) Nitrosyl Cation Radicals of Porphyrins, Chlorins, and Isobacteriochorins. Models for Nitrite and Sulfite Reductases and Implications for A1u Heme Radicals". . p. 7665 - 7669. Retrieved 1985.
• 4、 Damunupola, Dinusha,Chaudhri, Nivedita,Atoyebi, Adewole O.,Brückner, Christian. "Mechanochemical insertion of cobalt into porphyrinoids using Co2(CO)8as a cobalt source". supporting information. p. 3643 - 3652. Retrieved 2020/07/30.