Cobalt(1+), chloride

Base Information

• Chemical Name: Cobalt(1+), chloride
• CAS No.: 13876-90-9
• Molecular Formula: Cl*Cl₂CoH₁₂N₄
• Molecular Weight: 233.474
• NSC Number: 187632,187612,142042,40675,40674
• Mol file: 13876-90-9.mol

Synonyms:[Co](Cl)(Cl)(N)(N)(N)N;13820-60-5;Cobalt(1+), chloride;NSC40674;NSC40675;NSC-40674;NSC-40675;NSC142042;NSC187612;NSC187632;NSC-142042;NSC-187612;NSC-187632;Cobalt(1), tetraamminedichloro-, chloride;13876-90-9;24887-93-2;60955-47-7

Chemical Property of Cobalt(1+), chloride

Chemical Property:

• Hydrogen Bond Donor Count: 4
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 0
• Exact Mass: 192.945795
• Heavy Atom Count: 7
• Complexity: 9.7

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: [NH2-].[NH2-].[NH2-].[NH2-].Cl[Co]Cl

Technology Process of Cobalt(1+), chloride

There total 2 articles about Cobalt(1+), chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

octammine-μ-amino-ol-dicobalt(III) chloride * 4H2O → pentaaminechlorocobalt(III) dichloride (13859-51-3) + trans-[Co(NH3)4Cl2]Cl (13820-60-5,13876-90-9,24887-93-2)

Guidance literature:

With hydrogenchloride; sulfuric acid; In hydrogenchloride; sulfuric acid; longer storage of the chloride in a mixture of HCl and concd. H2SO4;;

Reference yield:

hydrogenchloride (7647-01-0,15364-23-5) + carbonatotetramminecobalt(III) chloride → pentaaminechlorocobalt(III) dichloride (13859-51-3) + trans-[Co(NH3)4Cl2]Cl (13820-60-5,13876-90-9,24887-93-2) + cis-{Co(NH3)4(H2O)Cl}Cl2

Guidance literature:

In water; treating a cold aq. soln. of {Co(NH3)4(CO3)}Cl with the same volume of HCl (1:1); prior to addn. of concd. HCl;;

Reference yield:

dichlorotetraammine cobalt(III) chloride (13876-90-9,24887-93-2,13820-60-5) → cobalt(II,III) oxide + cobalt(II) chloride (7646-79-9,14543-09-0,16413-89-1)

Guidance literature:

With oxygen; In solid; byproducts: N2, NH3, Cl2; thermal decompn. in air studied up to 1000°C; Kinetics;

DOI:10.1007/BF01914053

upstream raw materials:

hydrogenchloride

Downstream raw materials:

cobalt(II) chloride

cobalt