tert-butyl 4-fluorobenzoperoxoate

Base Information

• Chemical Name: tert-butyl 4-fluorobenzoperoxoate
• CAS No.: 56263-57-1
• Molecular Formula: C₁₁H₁₃FO₃
• Molecular Weight: 212.221
• Mol file: 56263-57-1.mol

Synonyms:tert-butyl 4-fluorobenzoperoxoate

Chemical Property of tert-butyl 4-fluorobenzoperoxoate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of tert-butyl 4-fluorobenzoperoxoate

There total 5 articles about tert-butyl 4-fluorobenzoperoxoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

tert.-butylhydroperoxide (75-91-2) + 4-fluorobenzylic alcohol (459-56-3) → tert-butyl 4-fluorobenzoperoxoate (56263-57-1)

Guidance literature:

With tetra-(n-butyl)ammonium iodide; In water; at 20 ℃; for 16h; Solvent;

DOI:10.1039/c5ra27500h

Reference yield: 82.0%

tert.-butylhydroperoxide (75-91-2) + 4-fluorophenylacetonitrile (459-22-3) → tert-butyl 4-fluorobenzoperoxoate (56263-57-1)

Guidance literature:

With copper diacetate; In neat (no solvent); at 20 ℃; for 5h; Green chemistry;

DOI:10.1039/c6ra27921j

Reference yield: 78.0%

tert.-butylhydroperoxide (75-91-2) + p-fluorotoluene (352-32-9) → tert-butyl 4-fluorobenzoperoxoate (56263-57-1)

Guidance literature:

With potassium iodide; In water; at 40 ℃; for 0.0166667h; Flow reactor; Green chemistry;

DOI:10.1021/acs.oprd.7b00248

upstream raw materials:

tert.-butylhydroperoxide

4-fluorobenzaldehyde

4-fluorobenzylic alcohol

4-fluorophenylacetonitrile

Downstream raw materials:

cyclohex-2-en-1-yl 4-fluorobenzoate

1-(tert-butyl)-4-(prop-1-en-1-yl)benzene

Refernces

• 1、 Li, Zhan-Ting,Liu, Yi,Wang, Hui,Wang, Ze-Kun,Xu, Zi-Yue,Zhang, Dan-Wei,Zhang, Yun-Chang. "A Woven Supramolecular Metal-Organic Framework Comprising a Ruthenium Bis(terpyridine) Complex and Cucurbit[8]uril: Enhanced Catalytic Activity toward Alcohol Oxidation". . p. 1498 - 1503. Retrieved 2020/08/05.
• 2、 Zhang, Hui,Dong, Dao-Qing,Hao, Shuang-Hong,Wang, Zu-Li. "Bu4NI-catalyzed construction of tert-butyl peresters from alcohols". . p. 8465 - 8468. Retrieved 2016/02/09.