Technology Process of N,N'-(ferrocene-1,1'-diyldimethylylidene)di(4-methoxyaniline)
There total 1 articles about N,N'-(ferrocene-1,1'-diyldimethylylidene)di(4-methoxyaniline) which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
In
neat (no solvent, solid phase);
(under N2, Schlenk); Fe-complex and ligand added to tube, ground at roomtemp., sealed, shaken for 30 min at room temp.; placed under high vac. overnight, washed with cold MeOH, recrystd. from cold MeOH; elem. anal.;
DOI:10.1016/j.jorganchem.2007.04.011
- Guidance literature:
-
In
not given;
ferrocene-compound reacted with NaBH4 as described in J. Organometallic Chem. 691 (2006) 987.; elem. anal.;
DOI:10.1016/j.poly.2006.09.093
- Guidance literature:
-
With
triethylamine;
In
dichloromethane;
(Schlenk) to a -78°C soln. of phenoxyacetyl chloride in anhyd. CH2Cl2 under Ar triethylamine was added dropwise, the mixt. was stirred for 30 min, imine in CH2Cl2 was added slowly dropwise, 30 min at 0°C, room temp. overnight; extd. with CH2Cl2, washed with 10% NaHCO3, brine, dried over MgSO4, evapd., overnight diethyl ether trituration; insepd. mixt. of 2:1 syn/anti-diastereomers; elem. anal.;
DOI:10.1039/b911450e
