Technology Process of 2-(3-methyl-4-chlorophenoxy)-1,12-dicarba-closo-dodecaborane
There total 1 articles about 2-(3-methyl-4-chlorophenoxy)-1,12-dicarba-closo-dodecaborane which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
Pd(dibenzylideneacetone)2; rac-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl; NaH;
In
1,4-dioxane;
(Ar); addn. of 3-methyl-4-chlorophenol to suspn. of NaH (60% dispersion in mineral oil) in dioxane, stirring at 90°C for 0.5 h, addn. of 2-iodo-p-carborane, Pd(dba)2 and BINAP, stirring at 90°C for <48 h; monitoring by TLC using petroleum ether as eluent, diluting with CH2Cl2,filtration, removal of solvent under vac., flash chromy. on silica gel using petroleum ether or CHCl3 as eluent; as oil; elem. anal.;
DOI:10.1021/om9001044
