1-Chloro-8-nitronaphthalene

Base Information

• Chemical Name: 1-Chloro-8-nitronaphthalene
• CAS No.: 602-37-9
• Molecular Formula: C10H6 Cl N O2
• Molecular Weight: 207.616
• European Community (EC) Number: 210-015-6
• NSC Number: 60274
• DSSTox Substance ID: DTXSID20208945
• Nikkaji Number: J252.490B
• Wikidata: Q83083093
• Mol file: 602-37-9.mol

Synonyms:1-Chloro-8-nitronaphthalene;602-37-9;Naphthalene, 1-chloro-8-nitro-;EINECS 210-015-6;NSC60274;8-Chlornitronaphthalin;1-Chloro-8-nitro-naphthalene;F0074-0022;SCHEMBL5068468;DTXSID20208945;1-Chloro-8-nitronaphthalene, 98%;NSC 60274;NSC-60274;AKOS002384332;BS-29241;CS-0213483;METHYL4-HYDROXY-4-METHYL-2-PENTYNOATE;AS-871/43476254;SR-01000004825;SR-01000004825-1

Chemical Property of 1-Chloro-8-nitronaphthalene

Chemical Property:

• Vapor Pressure: 0.000145mmHg at 25°C
• Melting Point: 95.8°C
• Refractive Index: 1.5790 (estimate)
• Boiling Point: 342.8°C at 760 mmHg
• Flash Point: 161.1°C
• PSA: 45.82000
• Density: 1.409g/cm³
• LogP: 3.92460
• XLogP3: 3.3
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 0
• Exact Mass: 207.0087061
• Heavy Atom Count: 14
• Complexity: 229

Purity/Quality:

98%min ^*data from raw suppliers

1-Chloro-8-nitronaphthalene 97% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC2=C(C(=C1)[N+](=O)[O-])C(=CC=C2)Cl

Technology Process of 1-Chloro-8-nitronaphthalene

There total 18 articles about 1-Chloro-8-nitronaphthalene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 55.0%

→ 1-chloro-8-nitro-naphthalene (602-37-9)

Guidance literature:

Reference yield: 36.0%

C11H8NO4Cl3 → 1-chloro-8-nitro-naphthalene (602-37-9)

Guidance literature:

With copper(l) chloride; In 1,2-dichloro-ethane; at 200 ℃; for 2h; microwave irradiation;

DOI:10.1002/anie.200603416

Reference yield:

1-Nitronaphthalene (86-57-7) → 1-chloro-8-nitro-naphthalene (602-37-9)

Guidance literature:

With chlorine; iron(III) chloride;

upstream raw materials:

1-Nitronaphthalene

8-nitro-1-naphthylamine

1-Chloronaphthalene

nitric acid

Downstream raw materials:

8-(benzyloxy)-1-chlornaphthalin

1-chloro-4,8-dinitronaphthalene

8-chloronaphthalen-1-amine

8-chloro-1-naphthol

Refernces

• 1、 Bull, James A.,Hutchings, Michael G.,Quayle, Peter. "A remarkably simple and efficient benzannulation reaction". . p. 1869 - 1872. Retrieved 2008/03/12.