cyclohexa-1,4-diene

Base Information

• Chemical Name: cyclohexa-1,4-diene
• CAS No.: 1165952-92-0
• Molecular Formula: C₆H₈
• Molecular Weight: 80.1295
• Mol file: 1165952-92-0.mol

Synonyms:cyclohexa-1,4-diene

Chemical Property of cyclohexa-1,4-diene

Chemical Property:

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of cyclohexa-1,4-diene

There total 73 articles about cyclohexa-1,4-diene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 64.0%

benzene (71-43-2,26181-88-4,54682-86-9,13967-78-7,174973-66-1) → cyclohexa-1,4-diene (1165952-92-0) + cyclohexene (110-83-8)

Guidance literature:

With lithium; ethylenediamine; isopropyl alcohol; at 85 - 95 ℃; for 0.333333h;

Reference yield: 64.0%

benzene (71-43-2,26181-88-4,54682-86-9,13967-78-7,174973-66-1) → cyclohexa-1,4-diene (1165952-92-0) + cyclohexene (110-83-8)

Guidance literature:

With lithium; ethylenediamine; isopropyl alcohol; at 85 - 95 ℃; for 0.333333h; Product distribution; var. amounts of reaction partners; also alkyl-substituted derivatives;

Reference yield: 45.8%

cyclohexa-1,3-diene (1165952-91-9) → cyclohexa-1,4-diene (1165952-92-0) + cyclohexene (110-83-8) + benzene (71-43-2,26181-88-4,54682-86-9,13967-78-7,174973-66-1)

Guidance literature:

With K₂[Ru₄(CO)13]/Ar on carbon Sibunit; at 100 ℃; for 20h; Reagent/catalyst; Inert atmosphere;

DOI:10.1007/s11172-014-0519-5

upstream raw materials:

quinoline

1,4-dibromocyclohexane

1,3-diaminocyclohexane

1,4-Cyclohexanediol

Downstream raw materials:

7,7-dichlorobicyclo<4.1.0>hept-3-ene

(1α,3β,5β,7α)-4,4,8,8-tetrabromotricyclo<5.1.0.0>octane

3-methyl-endo-bicyclo<2.2.2>oct-5-ene-2,3-dicarboxylic anhydride

(+/-)-trans-4,5-bis-benzoyloxy-cyclohexene

Refernces

• 1、 Giovannini,Wegmueller. "-". . p. 1142,1149. Retrieved 1959.
• 2、 Dewald, Robert R.,Jones, Steven R.,Schwartz, Brian S.. "1,4,7,10-Tetraoxacyclododecane. An Aprotic Solvent for the Alkali Metals". . p. 272 - 273. Retrieved 1980.
• 3、 Cromwell, E.F.,Liu, D.-J.,Vrakking, M.J.J.,Kung, A.H.,Lee, Y.T.. "Dynamics of H2 elimination from cyclohexadiene". . p. 297 - 307. Retrieved 1991.
• 4、 Dunogues et al.. "". . p. 127. Retrieved 1972.
• 5、 Dewald, R. R.,Jones, S. R.,Schwartz, B. S.. "Hydrogen Production from the Reaction of Solvated Electrons with Benzene in Water-Ammonia Mixtures". . p. 3272 - 3273. Retrieved 1980.
• 6、 Cole, Justin P.,Chen, Dian-Feng,Kudisch, Max,Pearson, Ryan M.,Lim, Chern-Hooi,Miyake, Garret M.. "Organocatalyzed Birch Reduction Driven by Visible Light". supporting information. p. 13573 - 13581. Retrieved 2020/09/03.
• 7、 Gentner, Thomas Xaver,R?sch, Bastian,Ballmann, Gerd,Langer, Jens,Elsen, Holger,Harder, Sjoerd. "Low Valent Magnesium Chemistry with a Super Bulky β-Diketiminate Ligand". supporting information. p. 607 - 611. Retrieved 2018/12/13.