[1,1'-Biphenyl]-4,4'-dicarbonyl dichloride

Base Information

• Chemical Name: [1,1'-Biphenyl]-4,4'-dicarbonyl dichloride
• CAS No.: 2351-37-3
• Molecular Formula: C14H8Cl2O2
• Molecular Weight: 279.122
• Hs Code.: 2917399090
• European Community (EC) Number: 219-085-2
• DSSTox Substance ID: DTXSID0062343
• Nikkaji Number: J208.143A
• Wikidata: Q72443702
• Mol file: 2351-37-3.mol

Synonyms:2351-37-3;4,4'-Biphenyldicarbonyl chloride;[1,1'-Biphenyl]-4,4'-dicarbonyl dichloride;biphenyl-4,4'-dicarbonyl dichloride;4-(4-carbonochloridoylphenyl)benzoyl chloride;4,4'-Bibenzoyl Chloride;[1,1'-Biphenyl]-4,4'-dicarbonyldichloride;C14H8Cl2O2;EINECS 219-085-2;(1,1'-Biphenyl)-4,4'-dicarbonyl dichloride;4,4'-Dibenzoyl Chloride;SCHEMBL727046;DTXSID0062343;4,4'-Bi[benzoic acid chloride];4,4'-Diphenyldicarbonyl Chloride;AMY14297;MFCD00058934;AKOS005068030;4,4'-biphenyldicarboxylic acid chloride;1,1'-biphenyl-4,4'-dicarbonyl chloride;4,4'-biphenyldicarboxylic acid dichloride;BS-16725;B1308;FT-0617004;FT-0700540;D84218;[1,1''-Biphenyl]-4,4''-Dicarbonyl Dichloride;A878219;1,1'-Biphenyl-4,4'-bis(carboxylic acid chloride);[1,1'-Biphenyl]-4,4'-dicarbonyl dichloride, AldrichCPR

Chemical Property of [1,1'-Biphenyl]-4,4'-dicarbonyl dichloride

Chemical Property:

• Vapor Pressure: 7.35E-07mmHg at 25°C
• Melting Point: 189 °C
• Refractive Index: 1.603
• Boiling Point: 407.8 °C at 760 mmHg
• Flash Point: 224.1 °C
• PSA: 34.14000
• Density: 1.344 g/cm³
• LogP: 4.11160
• Storage Temp.: Inert atmosphere,Store in freezer, under -20°C
• Solubility.: very faint turbidity in hot Toluene
• XLogP3: 5.4
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 3
• Exact Mass: 277.9901349
• Heavy Atom Count: 18
• Complexity: 282

Purity/Quality:

98% ^*data from raw suppliers

4,4'-Biphenyldicarbonyl Chloride ^*data from reagent suppliers

Safty Information:

• Pictogram(s): R34:Causes burns.
• Hazard Codes: Xi,N
• Statements: 36-38-50/53
• Safety Statements: 26-60-61

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC(=CC=C1C2=CC=C(C=C2)C(=O)Cl)C(=O)Cl

Technology Process of [1,1'-Biphenyl]-4,4'-dicarbonyl dichloride

There total 13 articles about [1,1'-Biphenyl]-4,4'-dicarbonyl dichloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

4,4'-diphenic acid (787-70-2) → 4,4'-biphenyldicarboxylic acid dichloride (2351-37-3)

Guidance literature:

With thionyl chloride; for 3h; Reflux;

DOI:10.1002/pola.26199

Reference yield: 22.0%

1,2-dichlorotetramethylsilane (4342-61-4) + terephthaloyl chloride (100-20-9) → p-(Chlorodimethylsilyl)benzoyl chloride (17902-45-3) + 4,4'-biphenyldicarboxylic acid dichloride (2351-37-3)

Guidance literature:

In 1,3,5-trimethyl-benzene; at 165 ℃;

DOI:10.1021/jo00307a005

Reference yield:

oxalyl dichloride (79-37-8) + biphenyl (92-52-4,1594-86-1) → 4,4'-biphenyldicarboxylic acid dichloride (2351-37-3)

Guidance literature:

oxalyl dichloride; With aluminum (III) chloride; In dichloromethane; at 15 ℃; for 0.333333h; Schlenk technique; Inert atmosphere;

biphenyl; In dichloromethane; for 1.16667h; Schlenk technique; Inert atmosphere;

DOI:10.1016/j.tetlet.2016.03.071

upstream raw materials:

4,4'-bis(trichloromethyl)biphenyl

Benzotrichlorid

4,4'-diphenic acid

1,2-dichlorotetramethylsilane

Downstream raw materials:

4,4'-bis(4,5-dihydro-1H-imidazol-2-yl)biphenyl

diethyl biphenyl-4,4'-dicarboxylate

N,N'-dimethyl-N,N'-diphenyl-biphenyl-4,4'-dicarboxamide

4,4'-bis<<(6-methylpyrid-2-yl)amino>carbonyl>biphenyl

Refernces

• 1、 Zhang, Zhao-Ming,Han, Fang-Fang,Zhang, Ran,Li, Nan,Ni, Zhong-Hai. "Design, syntheses and aggregation-induced emission properties of two new enlarged tetraarylethene-based luminogens". . p. 1917 - 1920. Retrieved 2016.
• 2、 Liu, Hong-Kai,Ren, Li-Jun,Wu, Han,Ma, Yong-Li,Richter, Sven,Godehardt, Michael,Kübel, Christian,Wang, Wei. "Unraveling the Self-Assembly of Heterocluster Janus Dumbbells into Hybrid Cubosomes with Internal Double-Diamond Structure". supporting information. p. 831 - 839. Retrieved 2019/01/23.
• 3、 Bera, Sourav Sekhar,Debbarma, Suvankar,Ghosh, Avick Kumar,Chand, Santanu,Maji, Modhu Sudan. "Cp?CoIII-Catalyzed syn-Selective C-H Hydroarylation of Alkynes Using Benzamides: An Approach Toward Highly Conjugated Organic Frameworks". . p. 420 - 430. Retrieved 2017/04/26.