Aramite

Base Information

• Chemical Name: Aramite
• CAS No.: 140-57-8
• Molecular Formula: C15H23 Cl O4 S
• Molecular Weight: 334.864
• Hs Code.: 29252900
• European Community (EC) Number: 690-073-0
• NSC Number: 404155
• UNII: 55619R6X8S
• DSSTox Substance ID: DTXSID3020097
• Nikkaji Number: J5.807F
• Wikidata: Q27155771
• ChEMBL ID: CHEMBL1903447
• Mol file: 140-57-8.mol

Synonyms:Aramite;Niagaramite;sulfurous acid, 2-(p-tert-butylphenoxy)-1-methylethyl 2-chloroethyl ester

Chemical Property of Aramite

Chemical Property:

• Vapor Pressure: 4.46E-07mmHg at 25°C
• Melting Point: -31.7oC
• Refractive Index: nD20 1.5100 to 1.5118; nD27 1.5075
• Boiling Point: 426.2°Cat760mmHg
• Flash Point: 211.6°C
• PSA: 63.97000
• Density: 1.195g/cm³
• LogP: 4.46780
• Storage Temp.: 0-6°C
• Solubility.: Chloroform (Slightly), Methanol (Slightly)
• XLogP3: 4.6
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 5
• Rotatable Bond Count: 9
• Exact Mass: 334.1005581
• Heavy Atom Count: 21
• Complexity: 311

Purity/Quality:

98%,99%, ^*data from raw suppliers

Aramite ^*data from reagent suppliers

Safty Information:

• Hazard Codes: F,Xn
• Statements: 11-36/37/38-48/20-62-40
• Safety Statements: 53-16-36/37/39-45-36/37-24/25-23

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Pesticides -> Other Insecticides
• Canonical SMILES: CC(COC1=CC=C(C=C1)C(C)(C)C)OS(=O)OCCCl
• Description: Aramite is a synthetic chlorinated hydrocarbon with molecular weight of 334.87 and density of 1.143 at 20°C. It is a clear, light-colored oil with melting point of 37.3
  C and boiling point of 175 °C at 0.1 mm Hg. The technical grade aramite is a dark amber liquid. Aramite is soluble at 0.000 1% (practically insoluble) in water but is miscible in many organic solvents. It was sold as mixture in organic solvents at different strengths for further dilution and use. Aramite was used as a pesticide (acaricide) to control mites in plants and animals. Aramite was initially introduced to market around 1950. It was mostly used between 1950 and 1954 in greenhouses in the United States. Its manufacture and use were voluntarily discontinued due to its carcinogenic potential according to a US Environmental Protection Agency (EPA) notice dated 12 April 1977. However, there are reports of bans of aramite use in a few European countries, in 1987 (Lithuania), 1996 (Poland), and 1999 (Estonia). There is no information on the production, import, registration, marketing, stockpiling, and use of aramite in Russia. Occupational exposure through dermal contact and inhalation was possible during its use.
• Uses: Miticide. Aramite was formerly used in control of mites (miticide) in citrus fruits, vegetables, and animals. Active mite stage was most sensitive to aramite toxicity. The death in mites was due to paralysis and disorganized movements of appendages, leading to detachment from the plant. Insects and mites other than Tetracychidae are not as sensitive to aramite. Mites exposed in the field to up to 21 applications were not found to develop resistance in mites, unlike other organochlorines where insects develop resistance rapidly. Aramite is rendered inactive when mixed with lime and other alkaline materials. Aramite was used in combination of other pesticides to control a wide range of mite species.

Technology Process of Aramite

There total 1 articles about Aramite which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

→ Acaracide (140-57-8)

Guidance literature:

With pyridine; benzene;