Fluorine nitrate

Base Information

• Chemical Name: Fluorine nitrate
• CAS No.: 7789-26-6
• Molecular Formula: FNO3
• Molecular Weight: 81.0033
• UNII: 1Q6BYH7F2B
• DSSTox Substance ID: DTXSID20228502
• Wikipedia: Fluorine nitrate
• Wikidata: Q5462857
• Mol file: 7789-26-6.mol

Synonyms:Fluorine nitrate;Nitroxy fluoride;nitrogen trioxyfluoride;7789-26-6;UNII-1Q6BYH7F2B;1Q6BYH7F2B;NITRYL HYPOFLUORITE;FLUORONITRATE;FONO2;FNO3;nitrogen trioxide fluoride;FLUORINE NITRATE [MI];F-N-O3;DTXSID20228502;Q5462857

Chemical Property of Fluorine nitrate

Chemical Property:

• Melting Point: -175°
• Refractive Index: 1.301
• Boiling Point: bp -45.9°
• PSA: 55.05000
• Density: 1.524g/cm³
• LogP: 0.60240
• Water Solubility.: soluble acetone [MER06]
• XLogP3: 1
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 0
• Exact Mass: 80.98622102
• Heavy Atom Count: 5
• Complexity: 36.6

Purity/Quality:

99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s): Strong oxidizing agent, liquid explodes on shock or friction.
• Hazard Codes: Strong oxidizing agent, liquid explodes on shock or friction.

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: [N+](=O)([O-])OF
• Uses: Fluorine nitrate is used in rocket propellants as an oxidizing agent. Oxidizing agent in rocket propellants. Fluorine nitrate (FNO3) is a strong oxidizing gas or liquid. In the liquid state it explodes by shock or friction. It is used as an oxidizer for rocket propellant fuels.

Technology Process of Fluorine nitrate

There total 4 articles about Fluorine nitrate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

caesium nitrate + chlorine pentafluoride (184851-42-1,478167-78-1,13637-63-3,676353-68-7,478167-76-9) → fluorine nitrate (7789-26-6) + nitrylfluoride (10022-50-1)

Guidance literature:

With cesium fluoride; In neat (no solvent); byproducts: ClF, CsClF4, F2; stainless-steel cylinder loaded with CsNO3 and CsF, ClF5 (excess) added at -196°C, cylinder agitated on a shaker at 25°C for 18d, cooled back to -196°C; fractional condensation;

Reference yield:

nitric acid (7697-37-2,78989-43-2) + fluorine (7782-41-4) → fluorine nitrate (7789-26-6) + hydrogen fluoride (7664-39-3,12381-92-9,32057-09-3,74835-82-8)

Guidance literature:

20°C;

Reference yield:

sodium nitrate (7631-99-4) + sulfuric acid (7664-93-9) + fluorine (7782-41-4) → fluorine nitrate (7789-26-6) + hydrogen fluoride (7664-39-3,12381-92-9,32057-09-3,74835-82-8)

Guidance literature:

In nitric acid; aq. HNO3; distn. of NaNO3 and H2SO4; sepn. of the nitrogen oxides by a stream of dry air; pure F2 is passed through very concd. HNO3 in an Al-vessel; explosion possible;; condensation in a cold trap (liq. air); fractional distn.;;

DOI:10.1021/ja01290a011

upstream raw materials:

nitric acid

fluorine

chlorine pentafluoride

sodium nitrate

Downstream raw materials:

sodium nitrate

difluoroether

oxygen

fluoride

Refernces

• 1、 Christe, Karl O.,Wilson, William W.,Wilson, Richard D.. "Reactions of chlorine fluorides and oxyfluorides with the nitrate anion and alkali-metal fluoride catalyzed decomposition of ClF5". . p. 675 - 677. Retrieved 2008/10/08.