pentane-2,2,4-tricarboxylic acid-2,2-diethyl ester-4-methyl ester

Base Information

• Chemical Name: pentane-2,2,4-tricarboxylic acid-2,2-diethyl ester-4-methyl ester
• CAS No.: 342806-74-0
• Molecular Formula: C₁₃H₂₂O₆
• Molecular Weight: 274.314
• Mol file: 342806-74-0.mol

Synonyms:pentane-2,2,4-tricarboxylic acid-2,2-diethyl ester-4-methyl ester

Chemical Property of pentane-2,2,4-tricarboxylic acid-2,2-diethyl ester-4-methyl ester

Chemical Property:

Purity/Quality:

97% ^*data from raw suppliers

2,2-Diethyl4-MethylPentane-2,2,4-tricarboxylate ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of pentane-2,2,4-tricarboxylic acid-2,2-diethyl ester-4-methyl ester

There total 3 articles about pentane-2,2,4-tricarboxylic acid-2,2-diethyl ester-4-methyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

methacrylic acid methyl ester (80-62-6,114512-63-9,143476-91-9,25188-98-1,9011-14-7) + Diethyl methylmalonate (609-08-5) → pentane-2,2,4-tricarboxylic acid-2,2-diethyl ester-4-methyl ester (342806-74-0)

Guidance literature:

Diethyl methylmalonate; With sodium methylate; In methanol; at 20 ℃; for 0.166667h;

methacrylic acid methyl ester; In methanol; at 20 ℃;

DOI:10.1055/s-2002-28510

Reference yield:

Diethyl methylmalonate (609-08-5) → pentane-2,2,4-tricarboxylic acid-2,2-diethyl ester-4-methyl ester (342806-74-0)

Guidance literature:

With ethanol; sodium ethanolate; anschliessend mit (+-)-β-Brom-isobuttersaeure-methylester;

DOI:10.1002/pol.1958.1202912023

Reference yield:

methacrylic acid methyl ester (80-62-6,114512-63-9,143476-91-9,25188-98-1,9011-14-7) + diethyl malonate (105-53-3) → pentane-2,2,4-tricarboxylic acid-2,2-diethyl ester-4-methyl ester (342806-74-0)

Guidance literature:

upstream raw materials:

Diethyl methylmalonate

methacrylic acid methyl ester

diethyl malonate

Downstream raw materials:

2,4-dimethylglutaric acid

(2S,4R)-5-hydroxy-2,4-dimethyl-N-[(S)-1-phenylethyl]pentanamide

(+/-)-anti-2,4-dimethylglutaric anhydride

(3R,5S)-3,5-dimethyldihydro-2H-pyran-2,6(3H)-dione

Refernces