Tripentyl phosphate

Base Information

• Chemical Name: Tripentyl phosphate
• CAS No.: 2528-38-3
• Molecular Formula: C15H33 O4 P
• Molecular Weight: 308.398
• Hs Code.: 2919900090
• European Community (EC) Number: 219-773-2
• NSC Number: 202805
• UNII: CQ87Q628UH
• DSSTox Substance ID: DTXSID3052698
• Nikkaji Number: J150.771K
• Wikidata: Q81985166
• Mol file: 2528-38-3.mol

Synonyms:Tripentyl phosphate;2528-38-3;Triamyl Phosphate;tri-n-Amylphosphate;Phosphoric acid, tripentyl ester;Phosphoric Acid Triamyl Ester;tri-n-pentyl phosphate;Phosphoric acid tri-N-amyl ester;EINECS 219-773-2;NSC 202805;Phosphoric acid tripentyl ester;NSC-202805;triamylphosphate;Triamylphosphat;MFCD00015348;tri-n-amyl phosphate;Tripentyl phosphate #;SCHEMBL56777;CQ87Q628UH;DTXSID3052698;QJAVUVZBMMXBRO-UHFFFAOYSA-;Pentyl phosphate ((C5H11O)3PO);NSC202805;AKOS015856750;Phosphoric acid, tripentyl ester (8CI);LS-107882;CS-0435528;FT-0730119;P0265;D91937;A937716;J-015908

Chemical Property of Tripentyl phosphate

Chemical Property:

• Vapor Pressure: 0.000545mmHg at 25°C
• Refractive Index: 1.4290 to 1.4320
• Boiling Point: 321.9°Cat760mmHg
• Flash Point: 162.3°C
• PSA: 54.57000
• Density: 0.965g/cm³
• LogP: 5.71490
• XLogP3: 4.6
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 15
• Exact Mass: 308.21164653
• Heavy Atom Count: 20
• Complexity: 208

Purity/Quality:

98% ^*data from raw suppliers

Triamyl Phosphate ^*data from reagent suppliers

Safty Information:

• Statements: 20/21/22-36/37/38
• Safety Statements: 26-36/37/39

MSDS Files:

Useful:

• Canonical SMILES: CCCCCOP(=O)(OCCCCC)OCCCCC

Technology Process of Tripentyl phosphate

There total 7 articles about Tripentyl phosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

pentan-1-ol (71-41-0) → tripentyl phosphate (2528-38-3)

Guidance literature:

With phosphorous; tetraethylammonium iodide; In water; acetonitrile; at 50 ℃; Electrolysis;

DOI:10.1016/j.jorganchem.2004.11.008

Reference yield: 87.3%

pentan-1-ol (71-41-0) → di-n-pentylphosphoric acid (3138-42-9) + tripentyl phosphate (2528-38-3)

Guidance literature:

With sodium hypophosphite; copper dichloride; at 94.9 ℃; for 1h;

Reference yield: 87.0%

pentan-1-ol (71-41-0) → 1-Chloropentane (543-59-9) + tripentyl phosphate (2528-38-3)

Guidance literature:

With phosphan; chlorine; at 20 ℃; Mechanism; Rate constant; Thermodynamic data; E_a, ΔS(excit.), var. temp.; also in the presence of pyridine;

upstream raw materials:

pentan-1-ol

sodium pentanolate

tripentyl phosphite

Downstream raw materials:

N-pentyl-N-phenylbenzamide

barium dipentyl phosphate

Refernces

• 1、 Pitchaiah,Sivaraman,Lamba, Neha,Madras, Giridhar. "Experimental determination and model correlation for the solubilities of trialkyl phosphates in supercritical carbon dioxide". . p. 51286 - 51295. Retrieved 2016.
• 2、 Polimbetova,Borangazieva. "Oxidizing alkoxylation of phosphine in alcoholic solutions of iodine". . p. 2079 - 2082. Retrieved 2007/10/03.