5,10,15,20-tetrakis(4-cyanophenyl)porphirin

Base Information

• Chemical Name: 5,10,15,20-tetrakis(4-cyanophenyl)porphirin
• CAS No.: 14609-51-9
• Molecular Formula: C₄₈H₂₆N₈
• Molecular Weight: 714.788
• Mol file: 14609-51-9.mol

Synonyms:5,10,15,20-tetrakis(4-cyanophenyl)porphirin

Chemical Property of 5,10,15,20-tetrakis(4-cyanophenyl)porphirin

Chemical Property:

• Melting Point: >27 °C
• Density: 1.46±0.1 g/cm3(Predicted)

Purity/Quality:

99% ^*data from raw suppliers

5,10,15,20-Tetrakis(4-cyanophenyl)porphyrin 98% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 5,10,15,20-tetrakis(4-cyanophenyl)porphirin

There total 7 articles about 5,10,15,20-tetrakis(4-cyanophenyl)porphirin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 46.0%

pyrrole (109-97-7,30604-81-0) + 4-cyanobenzaldehyde (105-07-7) → 5,10,15,20-tetrakis(4-cyanophenyl)porphirin (14609-51-9)

Guidance literature:

pyrrole; 4-cyanobenzaldehyde; With boron trifluoride diethyl etherate; In dichloromethane; at 20 ℃; for 2h;

With chloranil; In dichloromethane; for 2h; Heating;

DOI:10.1016/S0968-0896(02)00153-0

Reference yield: 6.7%

pyrrole (109-97-7,30604-81-0) + 4-cyanobenzaldehyde (105-07-7) → 5,10,15,20-tetrakis(4-cyanophenyl)porphirin (14609-51-9) + C48H26N8

Guidance literature:

pyrrole; 4-cyanobenzaldehyde; With methanesulfonic acid; In dichloromethane; for 0.5h;

With 2,3-dicyano-5,6-dichloro-p-benzoquinone; In dichloromethane; for 0.166667h;

DOI:10.1021/jo049199e

Reference yield: 1.5%

pyrrole (109-97-7,30604-81-0) + 4-hydroxy-benzaldehyde (123-08-0,65581-83-1) + 4-cyanobenzaldehyde (105-07-7) → 5-((4-hydroxylphenyl)-10,15,20-tris(4-cyanophenyl)porphyrin) + 5,10,15,20-tetrakis(4-cyanophenyl)porphirin (14609-51-9)

Guidance literature:

In propionic acid; for 1h; Reflux;

DOI:10.1142/S108842461100435X

upstream raw materials:

pyrrole

4-cyanobenzaldehyde

4-hydroxy-benzaldehyde

Downstream raw materials:

cobalt(II) 5,10,15,20-tetrakis(4-cyanophenyl)porphyrinate

5,10,15,20-tetrakis(p-cyanophenyl)zincporphyrin

5,10,15,20-tetrakis-(4-(ethynyl)phenyl)porphyrinzinc(II)

nickel meso-tetrakis(p-cyanophenyl)porphine

Refernces

• 1、 Shaw, Janet L.,Garrison, Shana A.,Aleman, Elvin A.,Ziegler, Christopher J.,Modarelli, David A.. "Synthesis and spectroscopy of a series of substituted N-confused tetraphenylporphyrins". . p. 7423 - 7427. Retrieved 2004.
• 2、 Yi, Jun-Dong,Xu, Rui,Chai, Guo-Liang,Zhang, Teng,Zang, Ketao,Nan, Bing,Lin, Hua,Liang, Yu-Lin,Lv, Jiangquan,Luo, Jun,Si, Rui,Huang, Yuan-Biao,Cao, Rong. "Cobalt single-atoms anchored on porphyrinic triazine-based frameworks as bifunctional electrocatalysts for oxygen reduction and hydrogen evolution reactions". . p. 1252 - 1259. Retrieved 2019.
• 3、 Cao, Rong,Hou, Ying,Huang, Yuan-Biao,Mao, Min-Jie,Meng, Dong-Li,Si, Duan-Hui,Zhang, Meng-Di. "Highly Selective Tandem Electroreduction of CO2 to Ethylene over Atomically Isolated Nickel–Nitrogen Site/Copper Nanoparticle Catalysts". . p. 25485 - 25492. Retrieved 2021.
• 4、 Cao, Rong,Chen, Jian-Xin,Huang, Yuan-Biao,Mao, Min-Jie,Wu, Qiu-Jin. "Integration of metalloporphyrin into cationic covalent triazine frameworks for the synergistically enhanced chemical fixation of CO2". . p. 8026 - 8033. Retrieved 2020/12/28.