C₂₉H₄₂O₆Si

Base Information

• Chemical Name: C₂₉H₄₂O₆Si
• CAS No.: 1338989-56-2
• Molecular Formula: C₂₉H₄₂O₆Si
• Molecular Weight: 514.734
• Mol file: 1338989-56-2.mol

Synonyms:C₂₉H₄₂O₆Si

Chemical Property of C₂₉H₄₂O₆Si

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₂₉H₄₂O₆Si

There total 7 articles about C₂₉H₄₂O₆Si which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

C21H34O5Si (1338989-55-1) + p-Methoxybenzyl bromide (2746-25-0) → C29H42O6Si (1338989-56-2)

Guidance literature:

With tetra-(n-butyl)ammonium iodide; sodium hydride; In tetrahydrofuran; at 0 - 24 ℃;

DOI:10.1016/j.tetlet.2011.08.051

Reference yield:

C11H12O4 → C29H42O6Si (1338989-56-2)

Guidance literature:

Multi-step reaction with 5 steps

1: dmap; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride / dichloromethane / 25 °C

2: tert.-butyl lithium / tetrahydrofuran / -78 °C

3: zinc(II) tetrahydroborate / diethyl ether / -78 - -30 °C

4: tert.-butylhydroperoxide; bis(acetylacetonate)oxovanadium / dichloromethane / 0 - 24 °C

5: tetra-(n-butyl)ammonium iodide; sodium hydride / tetrahydrofuran / 0 - 24 °C

With tert.-butylhydroperoxide; dmap; zinc(II) tetrahydroborate; bis(acetylacetonate)oxovanadium; tert.-butyl lithium; tetra-(n-butyl)ammonium iodide; sodium hydride; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; In tetrahydrofuran; diethyl ether; dichloromethane;

DOI:10.1016/j.tetlet.2011.08.051

Reference yield:

C13H17NO4 (1338989-47-1) → C29H42O6Si (1338989-56-2)

Guidance literature:

Multi-step reaction with 4 steps

1: tert.-butyl lithium / tetrahydrofuran / -78 °C

2: zinc(II) tetrahydroborate / diethyl ether / -78 - -30 °C

3: tert.-butylhydroperoxide; bis(acetylacetonate)oxovanadium / dichloromethane / 0 - 24 °C

4: tetra-(n-butyl)ammonium iodide; sodium hydride / tetrahydrofuran / 0 - 24 °C

With tert.-butylhydroperoxide; zinc(II) tetrahydroborate; bis(acetylacetonate)oxovanadium; tert.-butyl lithium; tetra-(n-butyl)ammonium iodide; sodium hydride; In tetrahydrofuran; diethyl ether; dichloromethane;

DOI:10.1016/j.tetlet.2011.08.051

upstream raw materials:

C₁₃H₁₇NO₄

C₂₁H₃₄O₅Si

p-Methoxybenzyl bromide

[(2S,4S)-2-phenyl-1,3-dioxan-4-yl]methanol

Downstream raw materials:

C₂₃H₂₈O₆

C₂₃H₃₀O₆

C₃₉H₄₈O₆Si

C₃₉H₄₆O₆Si

Refernces