acetyl(tetracarbonyl)cobalt

Base Information

• Chemical Name: acetyl(tetracarbonyl)cobalt
• CAS No.: 13964-92-6
• Molecular Formula: C₆H₃CoO₅
• Molecular Weight: 214.08
• Mol file: 13964-92-6.mol

Synonyms:acetyl(tetracarbonyl)cobalt

Chemical Property of acetyl(tetracarbonyl)cobalt

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

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Technology Process of acetyl(tetracarbonyl)cobalt

There total 2 articles about acetyl(tetracarbonyl)cobalt which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

[bis(triphenylphospine)nitrogen(1+)][Co(CO)4] (53433-12-8) → acetyliodotricarbonylcobaltate + acetyl(tetracarbonyl)cobalt (13964-92-6)

Guidance literature:

With methyl iodide; In dichloromethane; under Ar; cooled MeI added to stirred soln. Co-complex/CH2Cl2 at 0°C;

DOI:10.1016/0022-328X(86)84041-4

Reference yield:

potassium tetracarbonylcobaltate (14878-26-3) → acetyliodotricarbonylcobaltate + acetyl(tetracarbonyl)cobalt (13964-92-6)

Guidance literature:

With MeI; In tetrahydrofuran; under Ar; cooled MeI added to stirred soln. Co-complex/THF kept at 0°C, soln. turned dark brown, almost complete conversion in 10 min; not isolated, detected by IR-spect.;

DOI:10.1016/0022-328X(86)84041-4

Reference yield: 92.0%

1,10-Phenanthroline (66-71-7) + acetyl(tetracarbonyl)cobalt (13964-92-6) + bis(dibenzylideneacetone)-palladium(0) (32005-36-0) → (1,10-phenanthroline)(CH3CO)PdCo(CO)4

Guidance literature:

In toluene; Co-compd. in toluene was added to toluene soln. of Pd-complex at -35 °C, stirring for several min., toluene soln. of phenanthroline was added at same temp., stirring overnight; mixt. was evapd. to dryness in vac., residue was washed with hexane, recrystn. from benzene, elem. anal.;

DOI:10.1021/om000728o

upstream raw materials:

[bis(triphenylphospine)nitrogen⁽¹⁺⁾][Co(CO)4]

potassium tetracarbonylcobaltate

Downstream raw materials:

α-(2,4-Xylidin-1-yl)benzyl-phenylketon

N-(2,4-Dimethyl-phenyl)-N-(2-oxo-1,2-diphenyl-ethyl)-acetamide

2-(2,6-Dimethyl-phenylamino)-1,2-diphenyl-ethanone

N-(2,6-Dimethyl-phenyl)-N-(2-oxo-1,2-diphenyl-ethyl)-acetamide

Refernces