nitrosobenzene-d₅

Base Information

• Chemical Name: nitrosobenzene-d₅
• CAS No.: 18628-43-8
• Molecular Formula: C₆H₅NO
• Molecular Weight: 112.072
• Mol file: 18628-43-8.mol

Synonyms:nitrosobenzene-d₅

Chemical Property of nitrosobenzene-d₅

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of nitrosobenzene-d₅

There total 5 articles about nitrosobenzene-d₅ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 58.0%

nitrobenzene-d5 (4165-60-0) → nitrosobenzene-d5 (18628-43-8)

Guidance literature:

With ammonium chloride; zinc; In water; at 20 ℃; for 0.333333h; Inert atmosphere; Schlenk technique;

DOI:10.1021/acs.orglett.9b00502

Reference yield:

aniline-d5 (4165-61-1) → nitrosobenzene-d5 (18628-43-8)

Guidance literature:

With potassium peroxymonosulfate sulfate; In dichloromethane; water; at 20 ℃; for 0.5h; Inert atmosphere;

DOI:10.1016/j.tetlet.2021.153550

Reference yield:

N-hyroxylaminobenzene-d5 (121410-48-8) → nitrosobenzene-d5 (18628-43-8)

Guidance literature:

With iron(III) chloride; In water;

DOI:10.1016/j.tet.2008.06.008

upstream raw materials:

nitrobenzene-d5

N-hyroxylaminobenzene-d5

benzene-d6

aniline-d5

Downstream raw materials:

C-(3,5-Di-tert.-butyl-anilino)-N-(D₅)-phenyl-nitron

DPZOH

azobenzene-d₁₀

C₂₂H₁₃⁽²⁾H₅N₂O₃

Refernces

• 1、 Xiao, Yan,Wu, Xiaopeng,Wang, Hepan,Sun, Song,Yu, Jin-Tao,Cheng, Jiang. "Rhodium-Catalyzed Reaction of Azobenzenes and Nitrosoarenes toward Phenazines". supporting information. p. 2565 - 2568. Retrieved 2019/04/30.
• 2、 Pfister, Rolf,Ihalainen, Janne,Hamm, Peter,Kolano, Christoph. "Synthesis, characterization and applicability of three isotope labeled azobenzene photoswitches". scheme or table. p. 3508 - 3517. Retrieved 2009/02/05.