IrCl(CO)((C₆H₅)2PC₆H₄C(O)CHC(O)C(CH₃)3)2Cu

Base Information

• Chemical Name: IrCl(CO)((C₆H₅)2PC₆H₄C(O)CHC(O)C(CH₃)3)2Cu
• CAS No.: 91312-17-3
• Molecular Formula: C₅₁H₄₈ClCuIrO₅P₂
• Molecular Weight: 1094.11
• Mol file: 91312-17-3.mol

Synonyms:IrCl(CO)((C₆H₅)2PC₆H₄C(O)CHC(O)C(CH₃)3)2Cu

Chemical Property of IrCl(CO)((C₆H₅)2PC₆H₄C(O)CHC(O)C(CH₃)3)2Cu

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

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Technology Process of IrCl(CO)((C₆H₅)2PC₆H₄C(O)CHC(O)C(CH₃)3)2Cu

There total 3 articles about IrCl(CO)((C₆H₅)2PC₆H₄C(O)CHC(O)C(CH₃)3)2Cu which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 73.0%

trans-IrCl(CO)[(o-(diphenylphosphino)benzoyl)pinacolone]2 (81157-62-2) + copper(II) oenanthate (5128-10-9) → IrCl(CO)((C6H5)2PC6H4C(O)CHC(O)C(CH3)3)2Cu (91312-17-3)

Guidance literature:

In tetrahydrofuran; a soln. of Ir-complex in THF was added dropwise under inert atmosphere to Cu(OCO(CH2)5Me)2 in THF, mixt. was stirred for 10 min; hexane was added, soln. concd., crystals were collected; elem. anal.;

DOI:10.1021/ja00331a014

Reference yield:

IrCl(CO)((C6H5)2PC6H4C(O)CHC(O)C(CH3)3)2Cu (91312-17-3) → IrCl(CO)((C6H5)2PC6H4C(O)CHC(O)C(CH3)3)2Cu (91312-17-3)

Guidance literature:

In not given; dissolution in coordinating solvents; in weakly coordinating solvents the complex exists as an equil. mixt. of forms containing and not containing enolate-bridged Cu and Ir atoms;

DOI:10.1021/ja00331a014

Reference yield:

IrCl(CO)(((C6H5)2PC6H4C(O)CHC(O)C(CH3)3)2Cu)SO2 (91327-60-5) → IrCl(CO)((C6H5)2PC6H4C(O)CHC(O)C(CH3)3)2Cu (91312-17-3)

Guidance literature:

In not given; soln. of SO2 adduct was purged with nitrogen;

DOI:10.1021/ja00331a014

upstream raw materials:

trans-IrCl(CO)[(o-(diphenylphosphino)benzoyl)pinacolone]2

copper(II) oenanthate

IrCl(CO)(((C₆H₅)2PC₆H₄C(O)CHC(O)C(CH₃)3)2Cu)SO₂

Downstream raw materials:

IrCl(CO)(((C₆H₅)2PC₆H₄C(O)CHC(O)C(CH₃)3)2Cu)SO₂

Refernces