Tetradecyl acrylate

Base Information

• Chemical Name: Tetradecyl acrylate
• CAS No.: 21643-42-5
• Molecular Formula: C17H32O2
• Molecular Weight: 268.44
• Hs Code.: 29161290
• European Community (EC) Number: 244-491-1
• UNII: VRE8K887S7
• DSSTox Substance ID: DTXSID2066721
• Nikkaji Number: J107.541A
• Wikidata: Q81993301
• Mol file: 21643-42-5.mol

Synonyms:Tetradecyl acrylate;21643-42-5;Acrylic Acid Tetradecyl Ester;tetradecyl prop-2-enoate;2-Propenoic acid, tetradecyl ester;Tetradecyl Acrylate (stabilized with MEHQ);2-Propenoic acid, n-tetradecyl ester;33827-80-4;tetradecylacrylate;2-Propenoic acid,tetradecyl ester;Tetradecyl acrylate #;Tetradecyl 2-propenoate;SCHEMBL164269;Acrylic acid, tetradecyl ester;VRE8K887S7;DTXSID2066721;WAA64342;EINECS 244-491-1;(C17-H32-O2)x-;MFCD00673244;BS-23467;CS-0167396;T2265;Tetradecyl Acrylate, (stabilized with MEHQ);D92591;EC 244-491-1;J-014203;Tetradecyl Acrylate, >/=95%,stabilized with MEHQ

Chemical Property of Tetradecyl acrylate

Chemical Property:

• Vapor Pressure: 9.29E-05mmHg at 25°C
• Melting Point: 14 °C
• Refractive Index: 1.447
• Boiling Point: 339.3 °C at 760 mmHg
• Flash Point: 125.4 °C
• PSA: 26.30000
• Density: 0.872 g/cm³
• LogP: 5.41670
• Storage Temp.: Keep in dark place,Sealed in dry,Room Temperature
• Water Solubility.: 2μg/L at 20℃
• XLogP3: 7.3
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 15
• Exact Mass: 268.240230259
• Heavy Atom Count: 19
• Complexity: 211

Purity/Quality:

99.9% ^*data from raw suppliers

Tetradecyl Acrylate (stabilized with MEHQ) ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: CCCCCCCCCCCCCCOC(=O)C=C

Technology Process of Tetradecyl acrylate

There total 4 articles about Tetradecyl acrylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.5%

1-Tetradecanol (112-72-1) + acryloyl chloride (814-68-6,25189-84-8) → n-tetradecyl acrylate (21643-42-5)

Guidance literature:

With triethylamine; In tetrahydrofuran; at 0 - 20 ℃; Inert atmosphere;

DOI:10.1002/anie.201610209

Reference yield: 42.0%

1-Tetradecanol (112-72-1) + acrylic acid (79-10-7) → n-tetradecyl acrylate (21643-42-5) + 3-(tetradecyloxy)-3-oxopropyl acrylate

Guidance literature:

With sodium hydrogen sulfate; at 110 ℃; for 2h;

DOI:10.1007/s11743-015-1691-9

Reference yield:

1-Tetradecanol (112-72-1) + acrylic acid (79-10-7) → n-tetradecyl acrylate (21643-42-5)

Guidance literature:

With hydroquinone; In cyclohexane; at 60 - 140 ℃; for 6h; Temperature;

upstream raw materials:

1-Tetradecanol

acrylic acid

acryloyl chloride

Refernces

• 1、 -. "Preparation method for synthesizing high-carbon alkyl acrylate through catalyzing in-situ acid resin". Paragraph 0041; 0042; 0050-0057. . Retrieved 2018/11/27.
• 2、 Kumar, Pandari Phani,Nayak, Rati Ranjan,Kanjilal, Sanjit. "Synthesis and Surface Properties of a Novel Sodium 3-(3-Alkyloxy-3-oxopropoxy)-3-oxopropane-1-sulfonate at the Air-Water Interface". . p. 689 - 695. Retrieved 2015/06/23.