lithium diphenylcuprate

Base Information

• Chemical Name: lithium diphenylcuprate
• CAS No.: 23402-69-9
• Molecular Formula: C₁₂H₁₀Cu*Li
• Molecular Weight: 224.698
• Mol file: 23402-69-9.mol

Synonyms:lithium diphenylcuprate

Chemical Property of lithium diphenylcuprate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of lithium diphenylcuprate

There total 3 articles about lithium diphenylcuprate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

copper(l) iodide (7681-65-4) + phenyllithium (591-51-5) → Li(1+)*{Cu(C6H5)2}(1-)*LiI=Li{Cu(C6H5)2}*LiI (23402-69-9,113811-10-2)

Guidance literature:

In tetrahydrofuran; CuI is reacted with LiPh in THF;

Reference yield:

phenyllithium (591-51-5) + copper(I) bromide (7787-70-4) → lithium diphenylcuprate (23402-69-9)

Guidance literature:

In further solvent(s); prepn. in dimethyl sulfide;;

DOI:10.1021/ja00219a057

Reference yield:

→ lithium diphenylcuprate (23402-69-9)

Guidance literature:

DOI:10.1021/ja01045a049

upstream raw materials:

copper(l) iodide

phenyllithium

copper(I) bromide

Downstream raw materials:

trans-2-phenylcyclopentan-1-ol

(3-methyl-5-phenyl)-2-cyclopentenone

4,5-dihydro-2,2-dimethyl-5-phenyl-3(2H)-furanone

sec-Butylbenzene

Refernces

• 1、 Bertz, Steven H.,Dabbagh, Gary. "The "Gilman Reagent" Ph2CuLi and "Higher Order" Ph3CuLi2; 13C and 6Li NMR in Dimethyl Sulfide". . p. 3668 - 3670. Retrieved 2007/10/02.