Ethylphosphonothioic dichloride

Base Information

• Chemical Name: Ethylphosphonothioic dichloride
• CAS No.: 993-43-1
• Molecular Formula: C2H5Cl2PS
• Molecular Weight: 163.007
• European Community (EC) Number: 213-609-3
• UN Number: 2927
• UNII: X7NUN2K5DC
• DSSTox Substance ID: DTXSID6027347
• Nikkaji Number: J298.593D
• Wikidata: Q81983948
• Mol file: 993-43-1.mol

Synonyms:Ethylphosphonothioic dichloride;993-43-1;ethylphosphonothioyl dichloride;PHOSPHONOTHIOIC DICHLORIDE, ETHYL-;Phosphonothioic dichloride, P-ethyl-;EINECS 213-609-3;X7NUN2K5DC;ETHYL PHOSPHONO THIOIC DICHLORIDE;dichloro-ethyl-sulfanylidene-lambda5-phosphane;C2H5Cl2PS;UNII-X7NUN2K5DC;ethanethiophosphonic dichloride;C2-H5-Cl2-P-S;ethyl phosphonothioic dichloride;SCHEMBL1396268;Ethylphosphonodithioicdichlo ride;DTXSID6027347;ethylthiophosphonic acid dichloride;Ethylphosphinothioylidene dichloride;dichloro(ethyl)-??-phosphanethione;ethylphosphonothioic acid dichloride;DICHLOROETHYLPHOSPHINE SULFIDE;ETHYLTHIOPHOSPHONIC DICHLORIDE;dichloro-ethyl-sulfanylidenephosphorane;AKOS006274330;ETHYL PHOSPHONOTHIOYL DICHLORIDE;ETHYLPHOSPHONOTHIONIC DICHLORIDE;ETHYLTHIONOPHOSPHONYL DICHLORIDE;ETHANETHIOPHOSPHONODICHLORIDIC ACID;ETHANEPHOSPHONOTHIONODICHLORIDIC ACID;Ethyl phosphonothioic dichloride, anhydrous;LS-195285;EN300-204617;Ethyl phosphonothioic dichloride, anhydrous [NA2927] [Poison];Ethyl phosphonothioic dichloride, anhydrous [NA2927] [Poison]

Chemical Property of Ethylphosphonothioic dichloride

Chemical Property:

• Vapor Pressure: 1.84mmHg at 25°C
• Boiling Point: 171.6°C at 760 mmHg
• Flash Point: 57.6°C
• PSA: 41.90000
• Density: 1.401g/cm³
• LogP: 3.44400
• XLogP3: 3
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 1
• Exact Mass: 161.9226637
• Heavy Atom Count: 6
• Complexity: 75.6
• Transport DOT Label: Poison Inhalation Hazard Corrosive

Purity/Quality:

98%Min ^*data from raw suppliers

EthylthiophosphonicDichloride ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Toxic Gases & Vapors -> Acid Halides
• Canonical SMILES: CCP(=S)(Cl)Cl

Technology Process of Ethylphosphonothioic dichloride

There total 8 articles about Ethylphosphonothioic dichloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.0%

dichlorophosphinoethane (1498-40-4) → ethylphosphonothioic dichloride (993-43-1)

Guidance literature:

With aluminium trichloride;

Reference yield:

Ethylphosphonic dichloride (1066-50-8) → ethylphosphonothioic dichloride (993-43-1)

Guidance literature:

With tetraphosphorus decasulfide;

DOI:10.1097/01.LAB.0000017165.26718.60

Reference yield:

ethylaluminum dichloride (563-43-9) → ethylphosphonothioic dichloride (993-43-1)

Guidance literature:

With trichlorothiophosphine; In hexane; for 8h; Heating;

DOI:10.1016/j.tetasy.2006.03.009

upstream raw materials:

Ethylphosphonic dichloride

dichlorophosphinoethane

chloroethane

2,4-Diethyl-1,3,2λ⁵,4λ⁵-dithiadiphosphetan-2,4-dithion

Downstream raw materials:

C₁₅H₂₃N₂O₄PS

C₁₅H₂₃N₂O₄PS

C₁₄H₂₀ClN₂O₄PS

C₁₆H₂₅ClNO₂PS

Refernces

• 1、 Saeidian, Hamdollah,Babri, Mehran,Abdoli, Morteza,Sarabadani, Mansour,Ashrafi, Davood,Naseri, Mohammad Taghi. "Microsynthesis and electron ionization mass spectral studies of O(S)-alkyl N,N-dimethyl alkylphosphono(thiolo)thionoamidates for Chemical Weapons Convention verification". . p. 2805 - 2814. Retrieved 2013/01/15.
• 2、 Wu, Shao-Yong,Casida, John E.. "ASYMMETRIC SYNTHESIS OF (Rp)- AND (Sp)-2-ETHYL-, (Rp)-2-PENTYLOXY-, (Sp)-2-PENTYLTHIO- AND (Sp)-2-PENTYLAMINO-4H-1,3,2-BENZODIOXAPHOSPHORIN 2-OXIDES". . p. 129 - 138. Retrieved 2007/10/02.