cis-5,6-Dihydrodibenzo<1,2>diazocine

Base Information

• Chemical Name: cis-5,6-Dihydrodibenzo<1,2>diazocine
• CAS No.: 21372-42-9
• Molecular Formula: C₁₄H₁₂N₂
• Molecular Weight: 208.263
• Mol file: 21372-42-9.mol

Synonyms:cis-5,6-Dihydrodibenzo<1,2>diazocine

Chemical Property of cis-5,6-Dihydrodibenzo<1,2>diazocine

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of cis-5,6-Dihydrodibenzo<1,2>diazocine

There total 2 articles about cis-5,6-Dihydrodibenzo<1,2>diazocine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 64.0%

2,2'-ethylenedianiline (34124-14-6) → cis-5,6-Dihydrodibenzo<1,2>diazocine (21372-42-9) + 5,6-dihydrodibenzo-1,2-diazocine N-oxide (40754-26-5)

Guidance literature:

With 3-chloro-benzenecarboperoxoic acid; In dichloromethane; acetic acid; for 13h;

DOI:10.1021/jacs.9b08794

Reference yield: 42.0%

2-nitrobenzyl thiocyanate (85071-27-8) → cis-5,6-Dihydrodibenzo<1,2>diazocine (21372-42-9) + N,N'-Di-o-tolyl-diazene N-oxide (956-31-0,51284-68-5,116723-89-8) + 5,6-dihydrodibenzo-1,2-diazocine N-oxide (40754-26-5)

Guidance literature:

Electrolytic reduction in weakly alkaline medium;

Reference yield: 89.0%

cis-5,6-Dihydrodibenzo<1,2>diazocine (21372-42-9) → 2,2'-ethylenedianiline (34124-14-6)

Guidance literature:

With pyridine; palladium on activated charcoal; hydrogen; In methanol; at 20 ℃; for 0.25h; under 760.051 Torr; Green chemistry;

DOI:10.1039/d1ob00850a

upstream raw materials:

2-nitrobenzyl thiocyanate

2,2'-ethylenedianiline

Downstream raw materials:

2,2'-ethylenedianiline

Refernces

• 1、 Hlavaty, Jaromir. "ELECTROLYTIC REDUCTION OF o-NITROBENZYL THIOCYANATE IN BUFFERED SOLUTIONS ON MERCURY". . p. 33 - 41. Retrieved 2007/10/02.