tungsten pentacarbonyl tetrahydrofuran

Base Information

• Chemical Name: tungsten pentacarbonyl tetrahydrofuran
• CAS No.: 36477-75-5
• Molecular Formula: C₉H₈O₆W
• Molecular Weight: 396.009
• Mol file: 36477-75-5.mol

Synonyms:tungsten pentacarbonyl tetrahydrofuran

Chemical Property of tungsten pentacarbonyl tetrahydrofuran

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

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Technology Process of tungsten pentacarbonyl tetrahydrofuran

There total 7 articles about tungsten pentacarbonyl tetrahydrofuran which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 30.0%

[(C5H5)(CO)3WS(CH3)W(CO)5] + hexafluoro-2-butyne (692-50-2) → tungsten hexacarbonyl (14040-11-0) + tungsten pentacarbonyl tetrahydrofuran (36477-75-5) + [W(C(CF3)C(CF3)COSCH3)(CO)2(C5H5)] (95099-35-7,71273-22-8,71357-05-6) + (C5H5)(CF2CCCF3)(OC)W(μ-SMe)W(CO)5

Guidance literature:

With THF; In tetrahydrofuran; Irradiation (UV/VIS); W2 complex in THF photolysed for 60 h with CF3C2CF3; chromd. (Florisil, hexane-CH2Cl2); elem. anal.;

Reference yield:

dimanganese decacarbonyl (10170-69-1) + dinatriumdecacarbonylwolframate → tungsten hexacarbonyl (14040-11-0) + pentacarbonylmanganate (35816-56-9,14971-26-7,71564-22-2) + tungsten pentacarbonyl tetrahydrofuran (36477-75-5)

Guidance literature:

In tetrahydrofuran; Irradiation (UV/VIS); (Ar or N2); UV irradn. of soln. of W compd. and Mn complex; W and Mn compds. were detected IR spect.;

Reference yield:

(C5H5)Ir(CO)2W(CO)5 → tungsten pentacarbonyl tetrahydrofuran (36477-75-5) + (η5-cyclopentadienyl)dicarbonyliridium(I) (12192-96-0) + tungsten (7440-33-7)

Guidance literature:

In hexane; N2 atmosphere; 20 min;

DOI:10.1139/v99-131

upstream raw materials:

dimanganese decacarbonyl

hexafluoro-2-butyne

tetrahydrofuran

tungsten hexacarbonyl

Downstream raw materials:

W(CO)2[[(CH₃)3C₆H₂C]2P₂][[(CH₃)3C₆H₂CP]W(CO)5]

W(CO)4[(CH₃)3C₆H₂C]2P₂

((CO)5W)2((C(OCH₃)CHCH)2C₆H₄)

tris(2-methyl-2-propoxy)(2,2-dimethylpropylidyne)tungsten(VI)

Refernces

• 1、 Krahulic, Kelly E.,Enright, Gary D.,Parvez, Masood,Roesler, Roland. "A stable N-heterocyclic carbene with a diboron backbone". . p. 4142 - 4143. Retrieved 2007/10/03.
• 2、 Silavwe, Ned D.,Goldman, Alan S.,Ritter, Robin,Tyler, David R.. "Reduction of CO2 and other substrates using photochemical reactions of the W2(CO)102- complex". . p. 1231 - 1236. Retrieved 2008/10/08.