Iodine azide

Base Information

• Chemical Name: Iodine azide
• CAS No.: 14696-82-3
• Molecular Formula: IN3
• Molecular Weight: 168.925
• DSSTox Substance ID: DTXSID70163550
• Wikipedia: Iodine_azide
• Wikidata: Q1624428
• Mol file: 14696-82-3.mol

Synonyms:Iodine azide;Iodine azide (dry);14696-82-3;IODINEAZIDE;Iodine azide (dry) [Forbidden];iodine-azide;Iodine(I) azide;Iodine azide (I(N3));DTXSID70163550;Q1624428

Chemical Property of Iodine azide

Chemical Property:

• PSA: 16.72000
• LogP: 1.64670
• XLogP3: 2.1
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 0
• Exact Mass: 168.91369
• Heavy Atom Count: 4
• Complexity: 41.2

Purity/Quality:

98%,99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: [N-]=[N+]=NI

Technology Process of Iodine azide

There total 1 articles about Iodine azide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

cesium azide (22750-57-8) + (iodocyano)iodonium hexafluoroarsenate → iodine(I) azide (14696-82-3) + cesium hexafluoroarsenate (18424-16-3) + cyanogen iodide (506-78-5)

Guidance literature:

In further solvent(s); addn. of CsN3 in SO2ClF to (ICNI)AsF6 in SO2ClF, stirring (30 min); filtration, the byproducts being identified by gas-phase IR when the filtrate wa carefully evapd. to dryness;

Reference yield: 79.4%

(C6H5)3Sn(C5H5) + iodine(I) azide (14696-82-3) → triphenyltin azide (1158-51-6)

Guidance literature:

In tetrachloromethane; byproducts: C5H5I; (N2); heating (60°C), mixing; distn. (soln. concn., 10 mm Hg), crystn. (petroleum ether); elem. anal.;

Reference yield: 75.0%

iodine(I) azide (14696-82-3) + tri(p-tolyl)antimony (5395-43-7) → tri-p-tolylantimony iodine azide (106112-72-5)

Guidance literature:

In tetrachloromethane; addn. of freshly prepd. soln. of IN3 in CCl4 at -10°C to stirred soln. of (C6H4CH3)3Sb in CCl4 precooled to -10°C for 15 min under N2; stirring for 1 h at initial temp.; allowing to reach room temp.;; filtration; evapn. under reduced pressure; addn. of petroleum ether; cooling overnight; elem. anal.;;

DOI:10.1016/S0277-5387(00)84419-8

upstream raw materials:

cesium azide

Downstream raw materials:

hydrogen azide

triphenyltin azide

sodium iodide

nitrogen

Refernces