2-dodecyl di-o-nitrobenzyl phosphate

Base Information

• Chemical Name: 2-dodecyl di-o-nitrobenzyl phosphate
• CAS No.: 1133062-79-9
• Molecular Formula: C₂₆H₃₇N₂O₈P
• Molecular Weight: 536.562
• Mol file: 1133062-79-9.mol

Synonyms:2-dodecyl di-o-nitrobenzyl phosphate

Chemical Property of 2-dodecyl di-o-nitrobenzyl phosphate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2-dodecyl di-o-nitrobenzyl phosphate

There total 2 articles about 2-dodecyl di-o-nitrobenzyl phosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

rac-2-dodecanol (10203-28-8) + tetra-o-nitrobenzylpyrophosphate (1401995-67-2) → 2-dodecyl di-o-nitrobenzyl phosphate (1133062-79-9)

Guidance literature:

With titanium(IV) tetrabutoxide; N-ethyl-N,N-diisopropylamine; In dichloromethane; at 20 ℃; for 18h; Inert atmosphere;

DOI:10.1016/j.tet.2012.08.070

Reference yield: 23.0%

rac-2-dodecanol (10203-28-8) + bis-(2-nitrobenzyl)-N,N-diisopropylphosphoramidite (187600-98-2) → 2-dodecyl di-o-nitrobenzyl phosphate (1133062-79-9)

Guidance literature:

rac-2-dodecanol; bis-(2-nitrobenzyl)-N,N-diisopropylphosphoramidite; With 1H-tetrazole; phenyl isocyanate; In dichloromethane; acetonitrile; at 20 ℃; for 16h; Inert atmosphere;

With dihydrogen peroxide; In dichloromethane; water; acetonitrile; at 0 ℃; for 1h; Inert atmosphere;

DOI:10.1016/j.tetlet.2008.12.065

upstream raw materials:

rac-2-dodecanol

bis-(2-nitrobenzyl)-N,N-diisopropylphosphoramidite

tetra-o-nitrobenzylpyrophosphate

Refernces

• 1、 Brady, Patrick B.,Morris, Elizabeth M.,Fenton, Owen S.,Sculimbrene, Bianca R.. "Efficient catalyst turnover in the phosphitylation of alcohols with phosphoramidites". supporting information; experimental part. p. 975 - 978. Retrieved 2009/05/27.