Rh(acetone)(tris(2-(diphenylphosphino)ethyl)phosphine) tetrafluoroborate

Base Information

• Chemical Name: Rh(acetone)(tris(2-(diphenylphosphino)ethyl)phosphine) tetrafluoroborate
• CAS No.: 122874-55-9
• Molecular Formula: BF₄*C₄₅H₄₈OP₄Rh
• Molecular Weight: 918.481
• Mol file: 122874-55-9.mol

Synonyms:Rh(acetone)(tris(2-(diphenylphosphino)ethyl)phosphine) tetrafluoroborate

Chemical Property of Rh(acetone)(tris(2-(diphenylphosphino)ethyl)phosphine) tetrafluoroborate

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of Rh(acetone)(tris(2-(diphenylphosphino)ethyl)phosphine) tetrafluoroborate

There total 1 articles about Rh(acetone)(tris(2-(diphenylphosphino)ethyl)phosphine) tetrafluoroborate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Rh(acetone)2(cyclooctadiene) tetrafluoroborate (80951-12-8) + tris(2-diphenylphosphinoethyl)phosphine (23582-03-8) → Rh(acetone)(tris(2-(diphenylphosphino)ethyl)phosphine) tetrafluoroborate (122874-55-9)

Guidance literature:

With acetone; In acetone; N2; generated in situ; not isolated;

Reference yield: 77.0%

ammonium thiocyanate + Rh(acetone)(tris(2-(diphenylphosphino)ethyl)phosphine) tetrafluoroborate (122874-55-9) → RhNCS(tris(2-(diphenylphosphino)ethyl)phosphine) (122874-53-7)

Guidance literature:

In acetone; N2; excess of NH4NCS, soln. stirred overnight at room temp.; ppt. washed with EtOH/Et2O, dried in vac.;

Reference yield: 75.0%

Rh(acetone)(tris(2-(diphenylphosphino)ethyl)phosphine) tetrafluoroborate (122874-55-9) → RhCN(tris(2-(diphenylphosphino)ethyl)phosphine) (118681-54-2)

Guidance literature:

With NaCN; In acetone; N2; excess of NaCN, addn. of 15-crown-5, soln. stirred for 30 min at room temp.; ppt. washed with EtOH/Et2O, dried in vac.;

upstream raw materials:

Rh(acetone)2(cyclooctadiene) tetrafluoroborate

tris(2-diphenylphosphinoethyl)phosphine

Downstream raw materials:

{(PP₃)RhCl}

RhNCS(tris(2-(diphenylphosphino)ethyl)phosphine)

RhCN(tris(2-(diphenylphosphino)ethyl)phosphine)

Rh(pyridine)(tris(2-(diphenylphosphino)ethyl)phosphine) tetrafluoroborate

Refernces