Methyl propyl sulfide

Base Information

• Chemical Name: Methyl propyl sulfide
• CAS No.: 3877-15-4
• Molecular Formula: C4H10S
• Molecular Weight: 90.1894
• Hs Code.: 2930909090
• European Community (EC) Number: 223-403-5
• UNII: NXA8RQ27B3
• DSSTox Substance ID: DTXSID9073969
• Nikkaji Number: J44.106F
• Wikidata: Q27160229
• Mol file: 3877-15-4.mol

Synonyms:Methyl propyl sulfide;3877-15-4;Propane, 1-(methylthio)-;2-Thiapentane;Methyl propyl sulphide;1-methylsulfanylpropane;Sulfide, methyl propyl;1-(Methylthio)propane;METHYL N-PROPYL SULFIDE;1-(Methylthio)-propane;UNII-NXA8RQ27B3;NXA8RQ27B3;EINECS 223-403-5;METHYLPROPYLSULFIDE;methyl(propyl)sulfane;propyl methyl sulfide;1-(Methylsulfanyl)propane;n-C3H7SCH3;1-(Methylsulfanyl)propane #;DTXSID9073969;FEMA NO. 4889;CHEBI:88383;MFCD00015219;AKOS015897459;FT-0628765;M2285;D91585;A824275;Q27160229

Chemical Property of Methyl propyl sulfide

Chemical Property:

• Vapor Pressure: 54.7mmHg at 25°C
• Melting Point: -113 °C
• Refractive Index: n20/D 1.4430(lit.)
• Boiling Point: 94.1 °C at 760 mmHg
• Flash Point: 0 °C
• PSA: 25.30000
• Density: 0.831 g/cm³
• LogP: 1.75940
• Storage Temp.: Refrigerator, under inert atmosphere
• Solubility.: Chloroform, Methanol (Slightly)
• XLogP3: 1.8
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 2
• Exact Mass: 90.05032149
• Heavy Atom Count: 5
• Complexity: 13.1

Purity/Quality:

98% ^*data from raw suppliers

Methyl Propyl Sulfide ^*data from reagent suppliers

Safty Information:

• Pictogram(s): F,Xi
• Hazard Codes: F,Xi
• Statements: 11-36/37/38
• Safety Statements: 16-26-36

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCSC

Technology Process of Methyl propyl sulfide

There total 24 articles about Methyl propyl sulfide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

ethylmagnesium bromide (925-90-6) + dimethyl sulfoxide (67-68-5,8070-53-9) → dimethylsulfide (75-18-3) + Ethyl methyl sulfide (624-89-5) + 1-(methylthio)-propane (3877-15-4) + ethyl propyl sulfide (4110-50-3) + 2,4-dithiapentane (1618-26-4)

Guidance literature:

With magnesium bromide; In diethyl ether; at 36 ℃; for 5h; Product distribution; other reagent, reagents ratios;

DOI:10.1007/BF00957953

Reference yield:

chloro-methylsulfanyl-methane (2373-51-5) + ethylmagnesium bromide (925-90-6) → dimethylsulfide (75-18-3) + Ethyl methyl sulfide (624-89-5) + 1-(methylthio)-propane (3877-15-4) + ethyl propyl sulfide (4110-50-3)

Guidance literature:

In diethyl ether; at 36 ℃; for 5h; Product distribution;

DOI:10.1007/BF00957953

Reference yield:

diethylmagnesium (557-18-6) + dimethyl sulfoxide (67-68-5,8070-53-9) → dimethylsulfide (75-18-3) + Ethyl methyl sulfide (624-89-5) + 1-(methylthio)-propane (3877-15-4) + ethyl propyl sulfide (4110-50-3)

Guidance literature:

In diethyl ether; at 36 ℃; for 5h; Product distribution; reagents ratios;

DOI:10.1007/BF00957953

upstream raw materials:

1-thiopropane

methylthiol

propyl bromide

thiourea

Downstream raw materials:

benzyl-methyl-propyl sulfonium ; picrate

methyl n-propyl sulfoxide

(methylsulfonyl)propane

sulphonium

Refernces

• 1、 Beamer,Wynn,Rollins,Ledesma. "Biochemical interactions of dimethyl sulfoxide. II: Lactate dehydrogenase catalyzed reactions". . p. 1384 - 1386. Retrieved 1973.
• 2、 Ding, Jie,Dai, Zan,Tian, Fan,Zhou, Bo,Zhao, Bin,Zhao, Huiping,Chen, Zhiquan,Liu, Yunling,Chen, Rong. "Generation of VBr? VBi? VO?? defect clusters for 1O2 production for molecular oxygen activation in photocatalysis". supporting information. p. 23453 - 23459. Retrieved 2017/11/30.
• 3、 Turchaninova, L. P.,Korchevin, N. A.,Deryagina, E. N.,Trofimov, B. A.,Voronkov, M. G.. "GENERATION OF CHALCOGENIDE ANIONS IN HYDRAZINE HYDRATE MEDIUM". . p. 125 - 126. Retrieved 2007/10/02.