triethylsilyl benzoate

Base Information

• Chemical Name: triethylsilyl benzoate
• CAS No.: 1018-20-8
• Molecular Formula: C₁₃H₂₀O₂Si
• Molecular Weight: 236.386
• Mol file: 1018-20-8.mol

Synonyms:triethylsilyl benzoate

Chemical Property of triethylsilyl benzoate

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of triethylsilyl benzoate

There total 22 articles about triethylsilyl benzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

triethylsilane (617-86-7) + benzoic acid (65-85-0,8013-63-6) → triethylsilyl benzoate (1018-20-8)

Guidance literature:

With indium(III) bromide; In dichloromethane-d2; at 20 ℃;

DOI:10.1002/anie.201104140

Reference yield: 99.0%

triethylsilyl formate (18296-01-0) + benzoic acid (65-85-0,8013-63-6) → triethylsilyl benzoate (1018-20-8)

Guidance literature:

With [Ru(κ¹-OAc)(κ²-OAc)(κ³-1,1,1-tris(diphenylphosphinomethyl)ethane)]; In acetonitrile; at 70 ℃; for 2h; Solvent; Reagent/catalyst; Catalytic behavior; Inert atmosphere; Schlenk technique; Sealed tube;

Reference yield: 94.0%

triethylsilane (617-86-7) + 1,2:5,6-di-O-isopropylidene-3-O-(4-fluorophenoxy)thionocarbonyl-α-D-glucofuranose (130534-83-7) → 4-Fluorophenol (371-41-5) + triethylsilyl benzoate (1018-20-8) + triethyl(para-fluorophenoxy)silane + 3-deoxy-1,2;5,6-di-O-isopropylidene-α-D-glucofuranoside (4613-62-1)

Guidance literature:

With dibenzoyl peroxide; In toluene; Product distribution; Mechanism; Heating; other reagents, other substrates;

DOI:10.1016/S0040-4020(01)80380-X

upstream raw materials:

triethylsilane

benzoic acid

Benzoyl bromide

Benzoesaeure-α-chlorbenzylester

Downstream raw materials:

benzoic acid

methyl 3-hydroxy-2,2-dimethyl-3-phenylpropanoate

Refernces

• 1、 Sekiguchi, Akira,Kabe, Yoshio,Ando, Wataru. "Dye-Sensitized Photooxidation of Silyl Diazo Compounds. Intramolecular Oxygen Transfer of Carbonyl Oxides". . p. 2900 - 2903. Retrieved 1982.
• 2、 Liu, Guo-Bin. "Preparation of silyl esters by ZnCl2-catalyzed dehydrogenative cross-coupling of carboxylic acids and silanes". . p. 1431 - 1433. Retrieved 2006.
• 3、 Sekiguchi et al.. "". . p. 233. Retrieved 1979.
• 4、 -. "Use of Silylated Formiates as Hydrosilane Equivalents". . . Retrieved 2021/09/26.
• 5、 Chauvier, Clément,Godou, Timothé,Cantat, Thibault. "Silylation of O-H bonds by catalytic dehydrogenative and decarboxylative coupling of alcohols with silyl formates". . p. 11697 - 11700. Retrieved 2017/11/03.