diphenylphosphonic acid isoamyl ester

Base Information

• Chemical Name: diphenylphosphonic acid isoamyl ester
• CAS No.: 41044-86-4
• Molecular Formula: C₁₇H₂₁O₂P
• Molecular Weight: 288.326
• Mol file: 41044-86-4.mol

Synonyms:diphenylphosphonic acid isoamyl ester

Chemical Property of diphenylphosphonic acid isoamyl ester

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of diphenylphosphonic acid isoamyl ester

There total 7 articles about diphenylphosphonic acid isoamyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

bromobenzene (108-86-1,52753-63-6) + isopentyl phenylphosphinate (87025-54-5) → diphenylphosphonic acid isoamyl ester (41044-86-4)

Guidance literature:

With palladium diacetate; triethylamine; In neat (no solvent); at 150 ℃; for 0.0833333h; Microwave irradiation;

DOI:10.1039/c4ra03292f

Reference yield: 86.0%

3-methyl-1-butyl diphenylphosphinite (1202278-83-8) → diphenylphosphonic acid isoamyl ester (41044-86-4)

Guidance literature:

With dihydrogen peroxide; In water; benzene; at 20 - 25 ℃; for 1h; Inert atmosphere;

DOI:10.1016/j.tet.2009.10.008

Reference yield: 76.0%

i-Amyl alcohol (123-51-3) + diphenyl-phosphinic acid (1707-03-5) → diphenylphosphonic acid isoamyl ester (41044-86-4)

Guidance literature:

With copper(l) iodide; sodium carbonate; triethylamine; In tetrachloromethane; at 80 ℃; for 12h;

DOI:10.1021/cs501523g

upstream raw materials:

i-Amyl alcohol

Diphenylphosphinic chloride

3-methyl-1-butyl diphenylphosphinite

bromobenzene

Refernces

• 1、 Ye, Yang,Ma, Guobin,Yao, Ken,Gong, Hegui. "Zn-Mediated Hydrodeoxygenation of Tertiary Alkyl Oxalates". supporting information. p. 1625 - 1628. Retrieved 2021/01/18.
• 2、 Williams, D. Bradley G.,Netshiozwi, Takelani E.. "Synthesis and characterisation of severely hindered P-OR compounds". experimental part. p. 9973 - 9982. Retrieved 2010/02/27.