Methoxytri-n-butylstannane

Base Information

• Chemical Name: Methoxytri-n-butylstannane
• CAS No.: 1067-52-3
• Molecular Formula: C13H30 O Sn
• Molecular Weight: 321.091
• Hs Code.: 2931900090
• Mol file: 1067-52-3.mol

Synonyms:Methoxytri-n-butylstannane;Bu3SnOMe;tributyl tin methoxide;tri-n-butylmethoxy tin;methoxy(tri-n-butyl)tin;tri-n-butyl tin methoxide;Tributyltin(IV) methanolate;TRI-N-BUTYLTINMETHOXIDE;AMY6989;KJGLZJQPMKQFIK-UHFFFAOYSA-N;AKOS032949809;A801497

Chemical Property of Methoxytri-n-butylstannane

Chemical Property:

• Appearance/Colour: CLEAR COLOURLESS LIQUID
• Melting Point: 95-97℃
• Refractive Index: n20/D 1.472(lit.)
• Boiling Point: 97-97.5 °C0.06 mm Hg(lit.)
• Flash Point: 210 °F
• PSA: 9.23000
• Density: 1.115 g/mL at 25 °C(lit.)
• LogP: 4.97860
• Storage Temp.: under inert gas (nitrogen or Argon) at 2-8°C
• Sensitive.: Moisture Sensitive
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 9
• Exact Mass: 322.131868
• Heavy Atom Count: 15
• Complexity: 74.1

Purity/Quality:

98%,99%, ^*data from raw suppliers

Tributyltin methoxide 97% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): T,N
• Hazard Codes: T,N
• Statements: 21-25-36/38-48/23/25-50/53
• Safety Statements: 35-36/37/39-45-60-61

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: CCCC[Sn+](CCCC)CCCC.C[O-]
• Uses: For a review on tin reagents in organic synthesis see Aldrichimica Acta.

Technology Process of Methoxytri-n-butylstannane

There total 35 articles about Methoxytri-n-butylstannane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

methyl tributyltin carbonate (17207-78-2) → carbon dioxide (124-38-9,18923-20-1) + tributyltin methoxide (1067-52-3)

Guidance literature:

In not given; tin compd. was recovered at room temp. under vac.;

DOI:10.1021/om000397f

Reference yield: 98.0%

methanol (67-56-1) + allyltributylstanane (24850-33-7) → tributyltin methoxide (1067-52-3)

Guidance literature:

With trifluorormethanesulfonic acid; In dichloromethane; at room temp. for 23 h;

DOI:10.1246/cl.2002.152

Reference yield: 97.0%

methanol (67-56-1) + dimethylamino tributyltin (1067-24-9) → tributyltin methoxide (1067-52-3)

Guidance literature:

In diethyl ether; excess of CH3OH;

DOI:10.1016/S0022-328X(00)84649-5

upstream raw materials:

methanol

tributyltin chloride

sodium methylate

carbonic acid dimethyl ester

Downstream raw materials:

methyl (2R*,3S*)-3-benzylamino-2-(tert-butyldimethylsilyl)-4-methylpentanoate

sym-tetramethyldimethoxydisiloxane

1,3,3,3-tetrafluoro-1-methoxy-2-trifluoromethyl-propene

3-phenyl-1-(4-bromophenyl)-3-methoxy-1-propene

Refernces

• 1、 Davis, G. A.. "". . . Retrieved 1971.
• 2、 Ballivet-Tkatchenko,Douteau,Stutzmann. "Reactivity of carbon dioxide with n-butyl(phenoxy)-,(alkoxy)-, and (oxo)stannanes: insight into dimethyl carbonate synthesis". . p. 4563 - 4567. Retrieved 2000.
• 3、 Davies,Symes. "". . p. 394. Retrieved 1966.
• 4、 Kuivila,Sommer. "-". . p. 5616,5618. Retrieved 1967.
• 5、 Davis et al.. "". . p. 2179. Retrieved 1971.