1,1'-((C₅H₅)(P(m-Tol)3)2RuCCC₅H₄)2Ru

Base Information

• Chemical Name: 1,1'-((C₅H₅)(P(m-Tol)3)2RuCCC₅H₄)2Ru
• CAS No.: 934990-12-2
• Molecular Formula: C₁₀₈H₁₀₂P₄Ru₃
• Molecular Weight: 1827.1
• Mol file: 934990-12-2.mol

Synonyms:1,1'-((C₅H₅)(P(m-Tol)3)2RuCCC₅H₄)2Ru

Chemical Property of 1,1'-((C₅H₅)(P(m-Tol)3)2RuCCC₅H₄)2Ru

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of 1,1'-((C₅H₅)(P(m-Tol)3)2RuCCC₅H₄)2Ru

There total 1 articles about 1,1'-((C₅H₅)(P(m-Tol)3)2RuCCC₅H₄)2Ru which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

[(η5-C5H5)Ru(P(3-CH3-C6H4)3)2Cl] (204761-54-6) + 1,1'-bis[(trimethylsilyl)ethynyl]ruthenocene (158404-33-2) → 1,1'-((C5H5)(P(m-Tol)3)2RuCCC5H4)2Ru (934990-12-2)

Guidance literature:

With KF; In tetrahydrofuran; methanol; (N2); mixt. of Ru-P complex, Ru-Si complex and KF in MeOH/THF was refluxed for 16 h; cooled to room temp.; filtered; washed (MeOH, Et2O, hexane); elem. anal.;

DOI:10.1016/j.jorganchem.2006.11.037

Reference yield: 44.0%

1,1'-((C5H5)(P(m-Tol)3)2RuCCC5H4)2Ru (934990-12-2) + ethenetetracarbonitrile (670-54-2) → [((C5H5)(P(C6H4CH3)3)(CC(CN)2)2Ru(C5H4))2Ru] (935449-28-8,934990-32-6)

Guidance literature:

In dichloromethane; (N2); alkene was added to suspn. of Ru complex in CH2Cl2; mixt. was stirred for 2 d; solvent removed (vac.); chromd. (silica gel plates, acetone/CH2Cl2, 1/99); elem. anal.;

DOI:10.1016/j.jorganchem.2006.11.037

upstream raw materials:

[(η5-C5H5)Ru(P(3-CH3-C6H4)3)2Cl]

1,1'-bis[(trimethylsilyl)ethynyl]ruthenocene

Downstream raw materials:

[((C₅H₅)(P(C₆H₄CH₃)3)(CC(CN)2)2Ru(C₅H₄))2Ru]

Refernces