adamantane-2-thione

Base Information

• Chemical Name: adamantane-2-thione
• CAS No.: 23695-65-0
• Molecular Formula: C₁₀H₁₄S
• Molecular Weight: 166.287
• Mol file: 23695-65-0.mol

Synonyms:adamantane-2-thione

Chemical Property of adamantane-2-thione

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of adamantane-2-thione

There total 4 articles about adamantane-2-thione which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 25.0%

3-(2-adamantyl)-2,2-dimesityl-1,2-thiagermirane (107824-85-1) + 2,3-dimethyl-buta-1,3-diene (513-81-5) → 1,1-bis(2,4,6-trimethylphenyl)-3,4-dimethylgermacyclopent-3-ene (83686-73-1) + adamantane-2-thione (23695-65-0)

Guidance literature:

In benzene-d6; pyrolyzed at 495°C under flowing N2; Sepn. by preparative TLC;

DOI:10.1021/om00103a020

Reference yield:

2'-methyl-3',3'-diphenylspiro → adamantane-2-thione (23695-65-0) + N-methyl-diphenyl-nitrone (7500-79-0)

Guidance literature:

In chloroform-d1; at 25 ℃; Equilibrium constant;

DOI:10.1021/ja00143a008

Reference yield:

3-(2-adamantyl)-2,2-dimesityl-1,2-thiagermirane (107824-85-1) → tetrakis(2,4,6-trimethylphenyl)digermene (115385-07-4) + adamantane-2-thione (23695-65-0)

Guidance literature:

In solid matrix; Irradiation (UV/VIS); photochemical decompn. in hydrocarbon matrix (3-methylpentane) at 77K under Ar; thermally decompn.to dimesitylgermylene and adamantanethione; on annealing dimerisation of dimesitylgermylene; reaction followed by UV-VIS;

DOI:10.1021/om00103a020

upstream raw materials:

3-(2-adamantyl)-2,2-dimesityl-1,2-thiagermirane

2,3-dimethyl-buta-1,3-diene

C₁₀H₁₄SGe(C₆H₂(CH₃)3)2

Downstream raw materials:

2-Adamantanone

dispirodithietane-4',2''-adamantane>

C₁₄H₂₀OS

C₁₈H₁₉NO₂S

Refernces

• 1、 Tsumuraya, Takeshi,Sato, Sadao,Ando, Wataru. "Synthesis and chemistry of thiagermiranes". . p. 161 - 167. Retrieved 2008/10/08.