Thiocyclam hydrogen oxalate

Base Information

• Chemical Name: Thiocyclam hydrogen oxalate
• CAS No.: 31895-22-4
• Deprecated CAS: 84523-35-3
• Molecular Formula: C5H11NS3^.C2H2O4
• Molecular Weight: 271.383
• Hs Code.: 2934999090
• European Community (EC) Number: 250-859-2
• UNII: G3LOM1T4X9
• DSSTox Substance ID: DTXSID0047036
• Wikidata: Q27278701
• ChEMBL ID: CHEMBL2270412
• Mol file: 31895-22-4.mol

Synonyms:Evisect;Evisect hydrochloride;Evisect, oxalate(1:1) salt;Evisekt

Chemical Property of Thiocyclam hydrogen oxalate

Chemical Property:

• Appearance/Colour: colourless crystalline
• Vapor Pressure: 5.45 x 10-4 Pa (20 °C)
• Melting Point: 125-128oC
• Boiling Point: 280.7 °C at 760 mmHg
• PKA: 3.95 (acid), 7.0 (base)
• Flash Point: 123.6 °C
• PSA: 153.74000
• LogP: 1.11540
• Storage Temp.: 0-6°C
• Water Solubility.: 16.3 g l-1(20 °C, pH 6.8)
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 8
• Rotatable Bond Count: 2
• Exact Mass: 271.00067142
• Heavy Atom Count: 15
• Complexity: 152

Purity/Quality:

99.9% ^*data from raw suppliers

ThiocyclamOxalate ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xn, N
• Hazard Codes: Xn,N
• Statements: 21/22-50/53
• Safety Statements: 36/37-46-60-61

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CN(C)C1CSSSC1.C(=O)(C(=O)O)O
• Uses: Thiocyclam is used to protect against Lepidoptera, Coleoptera, some Diptera and Thysanoptera. It is used to control Colorado beetle in potatoes, Lepidoptera and Coleoptera pest complexes in rape, stem borers in irrigated rice, corn borers and Tanymecus in maize, weevils and other Coleoptera in sugar beet, stem borers in sugar cane, Lepidoptera in fruit trees and leaf miners in vegetables. Thiocyclam (trade name Evisect) is a broad-spectrum nereistoxin analogue insecticide used widely for agricultural applications.

Technology Process of Thiocyclam hydrogen oxalate

There total 1 articles about Thiocyclam hydrogen oxalate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

4-N,N-dimethylamino-1,2-dithiolane oxalate (1631-52-3) → N,N-dimethyl-1,2,3-trithiacyclohexane-5-amine oxalate (31895-22-4)

Guidance literature:

With sodium tetrathionate; for 15h; Ambient temperature; two phases system, 1m phosphate buffer pH 7,8 / diethyl ether, further reagent Na₂S₃O₆*3H₂O;

upstream raw materials:

4-N,N-dimethylamino-1,2-dithiolane oxalate

Refernces