Dimethyl-(3-phenyl-oxiranyl)-silanol

Base Information

• Chemical Name: Dimethyl-(3-phenyl-oxiranyl)-silanol
• CAS No.: 119873-76-6
• Molecular Formula: C₁₀H₁₄O₂Si
• Molecular Weight: 194.305
• Mol file: 119873-76-6.mol

Synonyms:Dimethyl-(3-phenyl-oxiranyl)-silanol

Chemical Property of Dimethyl-(3-phenyl-oxiranyl)-silanol

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Dimethyl-(3-phenyl-oxiranyl)-silanol

There total 5 articles about Dimethyl-(3-phenyl-oxiranyl)-silanol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 50.0%

(E)-2-(phenyl)ethylenyldimethylsilanol (119873-74-4) → Dimethyl-(3-phenyl-oxiranyl)-silanol (119873-76-6)

Guidance literature:

With titanium(IV) isopropylate; tert.-butylhydroperoxide; diethyl (2R,3R)-tartrate; In dichloromethane; at -20 ℃; for 40h;

DOI:10.1039/c39880001280

Reference yield:

(E)-2-phenylethenyllithium (4843-72-5,6160-69-6,62839-69-4) → Dimethyl-(3-phenyl-oxiranyl)-silanol (119873-76-6)

Guidance literature:

Multi-step reaction with 3 steps

1: 92 percent / diethyl ether / -20 °C

2: 71 percent / silver nitrate, silver oxide / tetrahydrofuran / 9 h / Ambient temperature

3: 50 percent / Ti(OiPr)4, (+)-DET, TBHP / CH₂Cl₂ / 40 h / -20 °C

With titanium(IV) isopropylate; tert.-butylhydroperoxide; diethyl (2R,3R)-tartrate; silver nitrate; silver(l) oxide; In tetrahydrofuran; diethyl ether; dichloromethane;

DOI:10.1039/c39880001280

Reference yield:

β-styrylchloromethyldimethylsilane (104891-66-9) → Dimethyl-(3-phenyl-oxiranyl)-silanol (119873-76-6)

Guidance literature:

Multi-step reaction with 3 steps

1: 73 percent / 20 h / 80 °C

2: TBHP/VO(acac)2 / acetone

3: 50 percent / Ti(OiPr)4, (+)-DET, TBHP / CH₂Cl₂ / 40 h / -20 °C

With titanium(IV) isopropylate; tert.-butylhydroperoxide; bis(acetylacetonate)oxovanadium; diethyl (2R,3R)-tartrate; In dichloromethane; acetone;

DOI:10.1039/c39880001280

upstream raw materials:

(E)-2-(phenyl)ethylenyldimethylsilanol

(E)-2-phenylethenyllithium

β-styrylchloromethyldimethylsilane

(E)-dimethyl(2-phenylethenyl)silane

Downstream raw materials:

(S)-styrene oxide

Refernces