Thuliumion(3+)

Base Information

• Chemical Name: Thuliumion(3+)
• CAS No.: 22541-23-7
• Molecular Formula: Tm
• Molecular Weight: 168.934
• Mol file: 22541-23-7.mol

Synonyms:Thuliumion(3+); Thulium(3+); Thulium(3+) ion; Tm3+

Chemical Property of Thuliumion(3+)

Chemical Property:

• PSA: 0.00000
• LogP: 0.00000

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Thuliumion(3+)

There total 4 articles about Thuliumion(3+) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

thulia → thulium(3+) (14041-47-5,14041-46-4,14333-45-0,15690-75-2,15720-75-9,15832-57-2,22541-23-7,7440-30-4,13598-55-5,13981-30-1)

Guidance literature:

With hydrochloric acid; In water; dissolving of Tm2O3 in concd. hydrochloric acid, diluting with H2O;

DOI:10.1134/S0036023611070321

Reference yield:

diammonium phthalocyaninedisulfonate Tm(III) complex → thulium(3+) (14041-47-5,14041-46-4,14333-45-0,15690-75-2,15720-75-9,15832-57-2,22541-23-7,7440-30-4,13598-55-5,13981-30-1)

Guidance literature:

In water; byproducts: phthalocyanine; pH < 2.9; Kinetics;

Reference yield:

tetra-aquo (tetrakis-(N-methyl-4-pyridyl)porphyrino)thulium(III)(5+) + hydrogen cation → meso-tetrakis(N-methyl-4-pyridiniumyl)porphirin + thulium(3+) (14041-47-5,14041-46-4,14333-45-0,15690-75-2,15720-75-9,15832-57-2,22541-23-7,7440-30-4,13598-55-5,13981-30-1)

Guidance literature:

In water; acid solvolysis: 25°C, unbuffered below pH 1, dichloroacetic acid buffered for pH 1-2, monochloroacetic acid for pH 2-3.5, ionic strength 0.8 M (by LiNO3/HNO3); stopped-flow apparatus; spectrophotometric monitoring; Kinetics;

DOI:10.1039/c39880000666

upstream raw materials:

TmBr(C₄₄H₂₈N₄)

Refernces

• 1、 Atanassova. "Effect of the 18-crown-6 and benzo-18-crown-6 on the solvent extraction and separation of lanthanide(III) ions with 8-hydroxyquinoline". . p. 1304 - 1311. Retrieved 2008/10/09.