Technology Process of 3-Azido-3-(3,5-dinitro-phenyl)-3H-diazirine
There total 4 articles about 3-Azido-3-(3,5-dinitro-phenyl)-3H-diazirine which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
sodium azide; sodium 2-nitropropane;
In
dimethyl sulfoxide;
at 17 ℃;
for 0.0138889h;
DOI:10.1021/jo00079a014
- Guidance literature:
-
Multi-step reaction with 4 steps
1: 88 percent / NaOMe / 18 h / Ambient temperature
2: 83 percent / NH4Cl / methanol / 12 h / 55 - 60 °C
3: 7 percent / NaCl, NaOCl / dimethylsulfoxide; hexane; diethyl ether / 1.) 0 deg C, 1.5 h, 2.) room temp, 20 min.
4: NaN3, 2-nitropropane sodium salt / dimethylsulfoxide / 0.01 h / 17 °C
With
sodium hypochlorite; sodium azide; sodium methylate; sodium 2-nitropropane; ammonium chloride; sodium chloride;
In
methanol; diethyl ether; hexane; dimethyl sulfoxide;
DOI:10.1021/jo00079a014
- Guidance literature:
-
Multi-step reaction with 3 steps
1: 83 percent / NH4Cl / methanol / 12 h / 55 - 60 °C
2: 7 percent / NaCl, NaOCl / dimethylsulfoxide; hexane; diethyl ether / 1.) 0 deg C, 1.5 h, 2.) room temp, 20 min.
3: NaN3, 2-nitropropane sodium salt / dimethylsulfoxide / 0.01 h / 17 °C
With
sodium hypochlorite; sodium azide; sodium 2-nitropropane; ammonium chloride; sodium chloride;
In
methanol; diethyl ether; hexane; dimethyl sulfoxide;
DOI:10.1021/jo00079a014