Terbium(III) chloride hydrate

Base Information

• Chemical Name: Terbium(III) chloride hydrate
• CAS No.: 13798-24-8
• Molecular Formula: (x)Cl₃Tb*(x)H₂O
• Molecular Weight: 283.29
• Hs Code.: 28469000
• DSSTox Substance ID: DTXSID90583438
• Mol file: 13798-24-8.mol

Synonyms:Terbium(III) chloride hydrate;trichloroterbium;hydrate;19423-82-6;tbcl3-hydrate;Terbium (III) chloride,hydrous;Trichloroterbium--water (1/1);DTXSID90583438;Terbium chloride (TbCl3), hexahydrate (8CI,9CI);Terbium(III) chloride hydrate, 99.99% trace metals basis

Chemical Property of Terbium(III) chloride hydrate

Chemical Property:

• Appearance/Colour: white crystals.
• Melting Point: 145oC
• Boiling Point: 100 °C at 760 mmHg
• Flash Point: °C
• PSA: 55.38000
• Density: 4.35 g/mL at 25 °C(lit.)
• LogP: 1.68270
• Storage Temp.: 0-6°C
• Sensitive.: Hygroscopic
• Water Solubility.: SOLUBLE
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 281.84248
• Heavy Atom Count: 5
• Complexity: 8

Purity/Quality:

98%,99%, ^*data from raw suppliers

Terbium(III) chloride hexahydrate (99.9%-Tb) (REO) ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/38
• Safety Statements: 26-36-24/25

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: O.Cl[Tb](Cl)Cl
• Uses: Terbium Chloride has important role as an activator for green phosphors used in colour TV tubes, is also used in special lasers and as a dopant in solid-state devices. Chloride compounds can conduct electricity when fused or dissolved in water. Terbium(III) chloride hexahydrate is used in the primary chemical intermediates and in chemical research.

Technology Process of Terbium(III) chloride hydrate

There total 14 articles about Terbium(III) chloride hydrate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

hydrogenchloride (7647-01-0,15364-23-5) + terbium(III, IV) oxide + water (7732-18-5) → TbCl3*5H2O (13798-24-8,19423-82-6)

Guidance literature:

In hydrogenchloride; Tb4O7 was heated with concd. aq. HCl; soln. was evapd. to dryness in vacuo at 50°C;

DOI:10.1016/j.ica.2003.11.011

Reference yield:

hydrogenchloride (7647-01-0,15364-23-5) + terbium(III, IV) oxide → terbium(III) chloride hexahydrate (13798-24-8,19423-82-6)

Guidance literature:

With dihydrogen peroxide; In hydrogenchloride; oxide dissoln. (H2O2 continuously addn. during dissoln.), water boiling off (stirring), pptn. until thick slurry obtained, slurry cooling to room temp.; solid filtration off, vac. treating at 40°C (grinding, stirring);

Reference yield:

hydrogenchloride (7647-01-0,15364-23-5) + terbium(III) oxide + water (7732-18-5) → terbium(III) chloride hexahydrate (13798-24-8,19423-82-6)

Guidance literature:

In hydrogenchloride; lanthanide oxide dissolved in dilute HCl; dried;

DOI:10.1016/S0022-2860(02)00614-2

upstream raw materials:

hydrogenchloride

water

TbCl₃*3H₂O

TbCl₃*2H₂O

Downstream raw materials:

(TbCl₂(((H₃C)2N)3PO)4)⁽¹⁺⁾*B(C₆H₅)4^(1-)=(TbCl₂(((H₃C)2N)3PO)4)(B(C₆H₅)4)

sodium hydroxide

Refernces

• 1、 Li, Feng,Wang, Meng,Mi, Congcong,Yi, Kuiyu,Xu, Shukun. "Polyol-mediated synthesis and luminescence properties of CePO4:Tb3+ nanospindles". . p. L37-L39. Retrieved 2009.
• 2、 Zhao, Na,Wang, Shu-Ping,Ma, Rui-Xia,Gao, Zhi-Hua,Wang, Rui-Fen,Zhang, Jian-Jun. "Synthesis, crystal structure and properties of two ternary rare earth complexes with aromatic acid and 1,10-phenanthroline". . p. 338 - 342. Retrieved 2008.
• 3、 Wang, Juan-Fen,Ren, Ning,Meng, Fan-Tao,Zhang, Jian-Jun. "Preparation and thermal properties of lanthanide complexes with 2,3-dichlorobenzoic acid and 1,10-phenanthroline". . p. 118 - 123. Retrieved 2011.
• 4、 Jin,Tsutsumi,Deguchi,Machida,Adachi. "Preparation and luminescence characteristics of the europium and terbium complexes incorporated into a silica matrix using a sol-gel method". . p. [d]59-66. Retrieved 1997.
• 5、 Lin, Nana,Li, Huanrong,Wang, Yige,Feng, Yu,Qin, Dashan,Gan, Quanying,Chen, Shudong. "Luminescent triazine-containing bridged polysilsesquioxanes activated by lanthanide ions". . p. 4781 - 4785. Retrieved 2008.
• 6、 Lyszczek,Iwan. "Investigation of desolvation process in lanthanide dinicotinates". . p. 633 - 639. Retrieved 2011/04/22.