Nabam

Base Information

• Chemical Name: Nabam
• CAS No.: 142-59-6
• Molecular Formula: C₄H₆N₂S₄*2Na
• Molecular Weight: 256.349
• Hs Code.: 29302000
• European Community (EC) Number: 205-547-0
• UN Number: 3077,2588
• UNII: 0L6N5662WT
• DSSTox Substance ID: DTXSID5020603
• Wikidata: Q1430329
• ChEMBL ID: CHEMBL1318057
• Mol file: 142-59-6.mol

Synonyms:amobam;ethylenebis(dithiocarbamic acid) disodium salt;nabam;nabam, ammonium salt;nabam, calcium salt (1:1);nabam, diammonium salt;nabam, dipotassium salt;nabam, disodium salt;nabam, iron salt;nabam, potassium salt;nabam, sodium salt

Chemical Property of Nabam

Chemical Property:

• Appearance/Colour: clear colourless to light yellow liquid
• Vapor Pressure: Negligible
• Melting Point: 78-81oC
• Boiling Point: 308.2 °C at 760 mmHg
• Flash Point: 140.2 °C
• PSA: 138.84000
• Density: g/cm³
• LogP: 1.91220
• Storage Temp.: 0-6°C
• Water Solubility.: ca. 200 g l-1 (room temperature)
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 3
• Exact Mass: 255.92092146
• Heavy Atom Count: 12
• Complexity: 108
• Transport DOT Label: Class 9

Purity/Quality:

99%min ^*data from raw suppliers

Nabam ^*data from reagent suppliers

Safty Information:

• Pictogram(s): XnN
• Hazard Codes: Xn,N
• Statements: 36/37/38-50/53-43-37-22
• Safety Statements: 26-36/37/39-61-60-46-24/25-8

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Pesticides -> Dithiocarbamates (Pesticide)
• Canonical SMILES: C(CNC(=S)[S-])NC(=S)[S-].[Na+].[Na+]
• Uses: Plant fungicide, starting material for derivativesthat are also pesticides. Nabam provides protection against fungal diseases of cotton, capsicums and onions when applied to soil.

Technology Process of Nabam

There total 3 articles about Nabam which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

carbon disulfide (75-15-0,12122-00-8) + ethylenediamine (107-15-3,85404-18-8) → disodium ethylenebis(dithiocarbamate) (13036-89-0,22124-95-4,28216-83-3,142-59-6)

Guidance literature:

With sodium hydroxide; In water; for 3h; Ambient temperature;

DOI:10.1021/jo981382i

Reference yield:

carbon disulfide (75-15-0,12122-00-8) + ethoxylated pentaerythitol tetraacrylate (125634-77-7,51728-26-8) + ethylenediamine (107-15-3,85404-18-8) → C41H60N8O12S16(8-)*8Na(1+) + disodium ethylenebis(dithiocarbamate) (13036-89-0,22124-95-4,28216-83-3,142-59-6)

Guidance literature:

ethoxylated pentaerythitol tetraacrylate; ethylenediamine; In methanol; at 25 ℃; for 46h; Inert atmosphere;

carbon disulfide; With sodium hydroxide; In methanol; water; at 20 - 25 ℃; for 5h; Inert atmosphere;

Reference yield:

→ disodium ethylenebis(dithiocarbamate) (13036-89-0,22124-95-4,28216-83-3,142-59-6)

Guidance literature:

upstream raw materials:

carbon disulfide

ethylenediamine

ethoxylated pentaerythitol tetraacrylate

Downstream raw materials:

(C₆H₅)2SbS₂CNHCH₂CH₂NHCS₂Sb(C₆H₅)2

2C₆H₅^(1-)*Sn⁽⁴⁺⁾*S₂CNHCH₂CH₂NHCS₂^(2-) = (C₆H₅)2Sn(S₂CNHCH₂CH₂NHCS₂)

bis(tetraphenylphosphonium) ethylenebis(dithiocarbamate)

5,5'-dibenzyl-3,3'-ethane-1,2-diyl-bis-[1,3,5]thiadiazinane-2-thione

Refernces

• 1、 -. "Compound heavy metal chelating agent containing dithiocarboxylate functionalized ethoxylated pentaerythritol core hyperbranched polymer". Paragraph 0033-0035. . Retrieved 2020/12/13.
• 2、 -. "Fungicidal composition for seed dressing". . . Retrieved 2008/06/13.