poly(di-n-butylgermylene)

Base Information

• Chemical Name: poly(di-n-butylgermylene)
• CAS No.: 122951-56-8
• Molecular Formula: C₈H₁₈Ge
• Molecular Weight: 186.821
• Mol file: 122951-56-8.mol

Synonyms:poly(di-n-butylgermylene)

Chemical Property of poly(di-n-butylgermylene)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of poly(di-n-butylgermylene)

There total 1 articles about poly(di-n-butylgermylene) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

7,7-di-n-butyl-7-germanorbornadiene (122951-47-7) → poly(di-n-butylgermylene) (122951-56-8) + 1,2,3,4-tetraphenylnaphthalene (751-38-2)

Guidance literature:

In solid matrix; Irradiation (UV/VIS); quartz UV cell, degassing by three freeze-pump-thaw cycles, placing th cell int aquartz windowed Dewar filled with liquid N2, irradn. with a low-pressure mercury lamp (254 nm) at 77K in 3-methylpentane matrix, warming to room temp., recooling to 77K; not isolated, detd. by UV;

Reference yield:

tetrachloromethane (56-23-5) + poly(di-n-butylgermylene) (122951-56-8) → dibutyldichlorogermane (4593-81-1)

Guidance literature:

In cyclohexane; byproducts: CCl3CCl3; Irradiation (UV/VIS); photolysis of Ge-compd. in cyclohexane in the presence of CCl4 at 245 nm at room temp. for 30 min with a 110 W low pressure Hg arc lamp; Kinetics;

DOI:10.1021/om00014a002

upstream raw materials:

7,7-di-n-butyl-7-germanorbornadiene

Downstream raw materials:

dibutyldichlorogermane

Refernces