5,5-Bis(phenylsulfanyl)pentane-1,2,3,4-tetrol(non-preferred name)

Base Information

• Chemical Name: 5,5-Bis(phenylsulfanyl)pentane-1,2,3,4-tetrol(non-preferred name)
• CAS No.: 28697-82-7
• Molecular Formula: C17H20 O4 S2
• Molecular Weight: 352.4683
• NSC Number: 135754,109288,98787
• DSSTox Substance ID: DTXSID90294931
• Mol file: 28697-82-7.mol

Synonyms:28697-82-7;D-Ribose, diphenyl dithioacetal;5,5-bis(phenylsulfanyl)pentane-1,2,3,4-tetrol(non-preferred name);DTXSID90294931;NSC98787;NSC-98787;NSC109288;NSC135754;NSC-109288;NSC-135754

Chemical Property of 5,5-Bis(phenylsulfanyl)pentane-1,2,3,4-tetrol(non-preferred name)

Chemical Property:

• Vapor Pressure: 1.01E-16mmHg at 25°C
• Boiling Point: 629.6°C at 760 mmHg
• Flash Point: 304.8°C
• Density: 1.39g/cm³
• XLogP3: 2.3
• Hydrogen Bond Donor Count: 4
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 8
• Exact Mass: 352.08030146
• Heavy Atom Count: 23
• Complexity: 300

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)SC(C(C(C(CO)O)O)O)SC2=CC=CC=C2

Technology Process of 5,5-Bis(phenylsulfanyl)pentane-1,2,3,4-tetrol(non-preferred name)

There total 2 articles about 5,5-Bis(phenylsulfanyl)pentane-1,2,3,4-tetrol(non-preferred name) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

L-arabinose (5328-37-0) + thiophenol (108-98-5) → (2S,3S,4R)-5,5-bis(phenylthio)pentane-1,2,3,4-tetraol (28697-82-7)

Guidance literature:

With trifluoroacetic acid; In water; at 50 - 60 ℃; for 12h;

DOI:10.1021/acs.orglett.1c00424

Reference yield:

→ (2S,3S,4R)-5,5-bis(phenylthio)pentane-1,2,3,4-tetraol (28697-82-7)

Guidance literature:

Aus L-Arabinose mit Thiophenol und HCl;

DOI:10.1016/S0008-6215(00)84892-2

Reference yield: 99.0%

(2S,3S,4R)-5,5-bis(phenylthio)pentane-1,2,3,4-tetraol (28697-82-7) → (2S,3R)-5,5-bis(phenylthio)pent-4-ene-1,2,3-triol

Guidance literature:

With potassium carbonate; carbonic acid dimethyl ester; In methanol; at 20 ℃; for 12h; regioselective reaction;

DOI:10.1021/acs.orglett.1c00424

upstream raw materials:

L-arabinose

thiophenol

Refernces