diethyl (Z)-9-octadecene-1,18-dioate

Base Information

• Chemical Name: diethyl (Z)-9-octadecene-1,18-dioate
• CAS No.: 80060-80-6
• Molecular Formula: C₂₂H₄₀O₄
• Molecular Weight: 368.557
• Mol file: 80060-80-6.mol

Synonyms:diethyl (Z)-9-octadecene-1,18-dioate

Chemical Property of diethyl (Z)-9-octadecene-1,18-dioate

Chemical Property:

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of diethyl (Z)-9-octadecene-1,18-dioate

There total 2 articles about diethyl (Z)-9-octadecene-1,18-dioate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 61.0%

ethanol (64-17-5) + (9Z)-octadec-9-enedioic acid (20701-68-2) → diethyl (Z)-9-octadecene-1,18-dioate (80060-80-6)

Guidance literature:

In hexane; at 25 ℃; for 10h; lipase immobilized in a microemulsion-based gel;

DOI:10.1016/S0040-4039(00)61081-X

Reference yield:

oleic acid ethyl ester (111-62-6) → octadeca-9Z-ene (1779-13-1) + 1-Decene (872-05-9,17438-89-0,25189-70-2) + trans-9-decenoic acid ethyl ester (67233-91-4) + diethyl (Z)-9-octadecene-1,18-dioate (80060-80-6)

Guidance literature:

With ethene; C₃₂H₄₀Cl₂N₂ORu; at 70 ℃; for 5h; under 15001.5 Torr; Reagent/catalyst;

DOI:10.1021/acscatal.8b04783

Reference yield: 62.0%

diethyl (Z)-9-octadecene-1,18-dioate (80060-80-6) → (Z)-civetone (542-46-1)

Guidance literature:

diethyl (Z)-9-octadecene-1,18-dioate; With lithium hexamethyldisilazane; In tetrahydrofuran; for 3.33333h; Inert atmosphere; Glovebox; Flow reactor; Heating;

With water; sodium hydroxide; In tetrahydrofuran; at 80 ℃; for 18h; stereoselective reaction; Inert atmosphere; Glovebox; Flow reactor;

DOI:10.1002/anie.202106410

upstream raw materials:

ethanol

(9Z)-octadec-9-enedioic acid

oleic acid ethyl ester

Downstream raw materials:

(Z)-civetone

Refernces

• 1、 Nascimento, Maria da Graca,Rezende, Marcos Caroli,Vecchia, Roberto Dalla,Jesus, Paulo Cesar de,Aguiar, Lucia Maria Z.. "ENZYME-CATALYZED ESTERIFICATIONS IN MICROEMULSION-BASED ORGANO GELS". . p. 5891 - 5894. Retrieved 2007/10/02.