tris(p-anisyl)ylantimony diacetate

Base Information

• Chemical Name: tris(p-anisyl)ylantimony diacetate
• CAS No.: 545379-80-4
• Molecular Formula: C₂₅H₂₇O₇Sb
• Molecular Weight: 561.235
• Mol file: 545379-80-4.mol

Synonyms:tris(p-anisyl)ylantimony diacetate

Chemical Property of tris(p-anisyl)ylantimony diacetate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of tris(p-anisyl)ylantimony diacetate

There total 1 articles about tris(p-anisyl)ylantimony diacetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

tris(p-anisyl)antimony (21502-70-5) + acetic acid (64-19-7,77671-22-8) → tris(p-anisyl)ylantimony diacetate (545379-80-4)

Guidance literature:

With tert.-butylhydroperoxide; In diethyl ether; byproducts: t-BuOH, H2O; t-BuOOH was added dropwise to stirred cold (5-10°C) soln. of Sb-compound and acid in Et2O, kept in the dark for 24 h at room temp.; solvent was distilled off under reduced pressure, recrystd. from CHCl3/hexane; elem. anal.;

DOI:10.1016/S0022-328X(02)02179-4

Reference yield: 95.0%

phosphonic acid diethyl ester (762-04-9) + tris(p-anisyl)ylantimony diacetate (545379-80-4) → diethyl (p-methoxyphenyl)phosphonate (3762-33-2)

Guidance literature:

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; In 1,4-dioxane; at 60 ℃; for 6h; Inert atmosphere;

DOI:10.1248/cpb.c14-00727

Reference yield: 91.0%

carbon monoxide (201230-82-2) + tris(p-anisyl)ylantimony diacetate (545379-80-4) + phenylboronic acid (98-80-6) → 4-Methoxybenzophenone (611-94-9) + 4-methoxylbiphenyl (613-37-6)

Guidance literature:

tetrakis(triphenylphosphine) palladium⁽⁰⁾; In 1-methyl-pyrrolidin-2-one; at 60 ℃; for 6h;

DOI:10.1016/j.jorganchem.2008.05.039

upstream raw materials:

tris(p-anisyl)antimony

acetic acid

Downstream raw materials:

methyl p-methoxycinnamate

biphenyl

4-methoxylbiphenyl

4,4'-Dimethoxybiphenyl

Refernces