2,2,3,3,4,4,4-Heptafluorobutanoic acid; silver

Base Information

• Chemical Name: 2,2,3,3,4,4,4-Heptafluorobutanoic acid; silver
• CAS No.: 3794-64-7
• Molecular Formula: C4H F7 O2 . Ag
• Molecular Weight: 320.9
• Hs Code.: 2843290000
• European Community (EC) Number: 223-266-1
• NSC Number: 133454
• Mol file: 3794-64-7.mol

Synonyms:Silver heptafluorobutyrate;3794-64-7;Heptafluormaselnan stribrny;2,2,3,3,4,4,4-heptafluorobutanoic acid;silver;silver heptaflu-orobutyrate;Butanoic acid, silver salt;SCHEMBL623540;Butyric acid, silver(1+) salt;Butanoic acid, silver(1+) salt;WLN: QVXFFXFFXFFF &-AG-;NSC133454;NSC-133454;A823946;2,3,3,4,4,4-Heptafluorobutyric acid, silver(1+) salt

Chemical Property of 2,2,3,3,4,4,4-Heptafluorobutanoic acid; silver

Chemical Property:

• Melting Point: 292-294 °C(lit.)
• Boiling Point: 120.2°Cat760mmHg
• Flash Point: 18°C
• PSA: 26.30000
• Density: 1.679g/cm³
• LogP: 1.82680
• Sensitive.: Light Sensitive
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 9
• Rotatable Bond Count: 2
• Exact Mass: 320.89157
• Heavy Atom Count: 14
• Complexity: 217

Purity/Quality:

98%min ^*data from raw suppliers

Silver heptafluorobutyrate 97% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xi,T
• Statements: 41
• Safety Statements: 26-37/39

MSDS Files:

Useful:

• Canonical SMILES: C(=O)(C(C(C(F)(F)F)(F)F)(F)F)O.[Ag]

Technology Process of 2,2,3,3,4,4,4-Heptafluorobutanoic acid; silver

There total 3 articles about 2,2,3,3,4,4,4-Heptafluorobutanoic acid; silver which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 68.0%

heptafluorobutyric Acid (375-22-4) + silver(l) oxide (20667-12-3) → silver heptafluorobutyrate (3794-64-7)

Guidance literature:

In water; Ag2O was added to stirred soln. of ligand in water, stirred for 30 min; filtered, solvent was removed in vacuo over 4 h; elem. anal.;

DOI:10.1016/S0020-1693(01)00718-6

Reference yield:

heptafluorobutyric Acid (375-22-4) → silver heptafluorobutyrate (3794-64-7)

Guidance literature:

With silver(l) oxide; In diethyl ether;

DOI:10.1002/oms.1210161209

Reference yield:

heptafluorobutyric Acid (375-22-4) + silver carbonate → silver heptafluorobutyrate (3794-64-7)

Guidance literature:

In not given; dark room; filtered; washed (ethanol); filtrate evapd. (stream of cold air); recrystd.; elem. anal.; NMR;

DOI:10.1016/0040-6031(93)80136-X

upstream raw materials:

heptafluorobutyric Acid

silver(l) oxide

Downstream raw materials:

C₄F₇O₂^(1-)*C₁₆H₂₄N₅O₃⁽¹⁺⁾

((CH₃)4C₅H)2Fe⁽¹⁺⁾*C₃F₇CO₂^(1-)=[((CH₃)4C₅H)2Fe][C₃F₇CO₂]

silver

Refernces

• 1、 Rakhimov,Kutyga. "Synthesis of α-tert-butylperoxyethyl perfluorocarboxylates". . p. 2162 - 2163. Retrieved 2009/04/10.
• 2、 -. "Pesticidal polyhaloalkene derivatives". . . Retrieved 2008/06/13.