Tripiperidinophosphine

Base Information

• Chemical Name: Tripiperidinophosphine
• CAS No.: 13954-38-6
• Molecular Formula: C15H30N3P
• Molecular Weight: 283.397
• Hs Code.: 2933399090
• European Community (EC) Number: 802-861-5
• NSC Number: 99043
• UNII: GTG23C2S66
• DSSTox Substance ID: DTXSID60161080
• Nikkaji Number: J50.233B
• Wikidata: Q72514862
• Mol file: 13954-38-6.mol

Synonyms:Tripiperidinophosphine;13954-38-6;Tris(piperidino)phosphine;Phosphine, tripiperidino-;tri(piperidin-1-yl)phosphane;Tripiperidylphosphine;Phosphorous tripiperidide;Tris(1-piperidinyl)phosphine;Piperidine, 1,1',1''-phosphinidynetris-;NSC 99043;BRN 0154737;Tri(piperidin-1-yl)phosphine;GTG23C2S66;NSC-99043;Piperidine, 1,1',1''-phosphinidynetri-;Piperidine, phosphinidynetris-;NSC99043;Tripiperidinyl phosphine;NCIOpen2_006585;UNII-GTG23C2S66;SCHEMBL7946634;C15H30N3P;DTXSID60161080;C15-H30-N3-P;GEO-04572;MFCD01706607;1,1',1''-phosphanetriyltripiperidine;Piperidine,1',1''-phosphinidynetris-;WLN: T6NTJ AP- AT6NTJ&- AT6NTJ;LS-106084;1,1',1''-PHOSPHINIDYNETRIPIPERIDINE;1,1',1''-PHOSPHINIDYNETRIS(PIPERIDINE);1-[BIS(PIPERIDIN-1-YL)PHOSPHANYL]PIPERIDINE

Chemical Property of Tripiperidinophosphine

Chemical Property:

• Appearance/Colour: Gray-white power
• Vapor Pressure: 1.12E-05mmHg at 25°C
• Boiling Point: 370.2 °C at 760 mmHg
• Flash Point: 177.7 °C
• PSA: 23.31000
• LogP: 3.48470
• XLogP3: 3.2
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 3
• Exact Mass: 283.21773497
• Heavy Atom Count: 19
• Complexity: 213

Purity/Quality:

99% ^*data from raw suppliers

TRIPIPERIDINOPHOSPHINE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1CCN(CC1)P(N2CCCCC2)N3CCCCC3
• Uses: Tripiperidinophosphine is a useful intermediate in the preparation of cyclic bis-amidophosphites based on dihydroxynaphthalene and in the preparation of new heterofunctionalized resorcinarene derivatives.

Technology Process of Tripiperidinophosphine

There total 15 articles about Tripiperidinophosphine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

piperidine (110-89-4) → tripiperidino-phosphine (13954-38-6)

Guidance literature:

With phosphorus trichloride; In diethyl ether;

DOI:10.1039/c3gc40493e

Reference yield: 95.0%

piperidine (110-89-4) + hexaethylphosphoric triamide (2283-11-6) → tripiperidino-phosphine (13954-38-6)

Guidance literature:

at 70 ℃; for 10h;

DOI:10.1016/S0040-4039(00)82246-7

Reference yield: 41.0%

C30H46N4O2P2 (863650-25-3) → 2,6-dipiperidino-1,3,5,7-tetraoxa-2,6-diphospha-4,8(1,3)-dinaphthalenacyclooctaphane (914468-02-3) + tripiperidino-phosphine (13954-38-6)

Guidance literature:

DOI:10.1134/S1070363206020046

upstream raw materials:

piperidine

bis(piperidinyl)chlorophosphine

hexaethylphosphoric triamide

diethyl ether

Downstream raw materials:

2-oxo-2-(piperidin-1-yl)ethyl-carbamic acid benzyl ester

N',N',N''-Tri-pentamethylen-phosphortriamidothionat

6-(4-chloro-phenoxy)-2,2,2-tri-piperidin-1-yl-2H-2λ⁵-[1,3,4,5,2]thiatriazaphosphinine

6-(4-nitro-phenoxy)-2,2,2-tri-piperidin-1-yl-2H-2λ⁵-[1,3,4,5,2]thiatriazaphosphinine

Refernces

• 1、 Chu, Crystal K.,Lin, Tzu-Pin,Shao, Huiling,Liberman-Martin, Allegra L.,Liu, Peng,Grubbs, Robert H.. "Disentangling ligand effects on metathesis catalyst activity: Experimental and computational studies of ruthenium-aminophosphine complexes". . p. 5634 - 5643. Retrieved 2018/05/03.
• 2、 Alexandrova, Anastasia V.,Masek, Tomas,Polyakova, Svetlana M.,Cisarova, Ivana,Saame, Jaan,Leito, Ivo,Lyapkalo, Ilya M.. "Synthesis of electron-rich sterically hindered P1 phosphazene bases by the staudinger reaction". . p. 1811 - 1823. Retrieved 2013/04/10.