trans-2-methoxy-3-phenyloxirane

Base Information

• Chemical Name: trans-2-methoxy-3-phenyloxirane
• CAS No.: 21087-52-5
• Molecular Formula: C₉H₁₀O₂
• Molecular Weight: 150.177
• Mol file: 21087-52-5.mol

Synonyms:trans-2-methoxy-3-phenyloxirane

Chemical Property of trans-2-methoxy-3-phenyloxirane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of trans-2-methoxy-3-phenyloxirane

There total 5 articles about trans-2-methoxy-3-phenyloxirane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

cis-β-methoxystyrene (14371-19-8) → Methyl formate (107-31-3) + benzaldehyde (100-52-7) + trans-2-methoxy-3-phenyloxirane (21087-52-5)

Guidance literature:

With oxygen; Ambient temperature;

DOI:10.1246/bcsj.54.2330

Reference yield:

cis-β-methoxystyrene (14371-19-8) → Methyl formate (107-31-3) + benzaldehyde (100-52-7) + trans-2-methoxy-3-phenyloxirane (21087-52-5) + benzoic acid (65-85-0,8013-63-6)

Guidance literature:

With oxygen; for 4h; Product distribution; Mechanism; Ambient temperature; Irradiation; other alkoxy- and alkyl styrenes, also with radical inhibitors; other solvents;

DOI:10.1246/bcsj.54.2330

Reference yield:

1-(2-methoxyvinyl)benzene (4747-15-3) → 2-methoxy-3-phenyl-oxirane (21087-52-5)

Guidance literature:

With isobutyraldehyde; In acetonitrile; at 35 ℃; for 8h; under 760.051 Torr;

DOI:10.1016/j.ica.2011.03.056

upstream raw materials:

sodium methylate

2-Phenyl-1-trimethylsilanyl-2-trimethylsilanyloxy-ethanone

1-(2-methoxyvinyl)benzene

cis-β-methoxystyrene

Downstream raw materials:

phenyl-piperidin-1-yl-acetaldehyde

mandelaldehyde

2,2-dimethoxy-1-(phenyl)ethanol

phenyl-piperidino-acetaldehyde-(2,4-dinitro-phenylhydrazone)

Refernces

• 1、 Ricci, Alfredo,Fiorenza, Mariella,Degl Innocenti, Alessandro,Seconi, Giancarlo,Dembech, Pasquale,et al.. "Acylsilane durch Oxidation von Phosphoniumyliden; erste Synthese von Bis(trimethylsilyl)keton und dessen Anwendung als CO(2-)-Aequivalent". . p. 1068 - 1069. Retrieved 2007/10/02.