4-(But-3-en-1-yl)-N,N-diMethylaniline

Base Information

• Chemical Name: 4-(But-3-en-1-yl)-N,N-diMethylaniline
• CAS No.: 344408-47-5
• Molecular Formula: C₁₂H₁₇N
• Molecular Weight: 175.274
• Mol file: 344408-47-5.mol

Synonyms:4-(but-3-enyl)-N,N-dimethylaniline

Chemical Property of 4-(But-3-en-1-yl)-N,N-diMethylaniline

Chemical Property:

• Storage Temp.: 2-8°C

Purity/Quality:

4-(But-3-en-1-yl)-N,N-dimethylaniline 95+% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 4-(But-3-en-1-yl)-N,N-diMethylaniline

There total 5 articles about 4-(But-3-en-1-yl)-N,N-diMethylaniline which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

4-bromo-N,N-dimethylaniline (586-77-6) + 4-but-1-enylmagnesium bromide (7103-09-5) → 4-(but-3-enyl)-N,N-dimethylaniline (344408-47-5)

Guidance literature:

With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; In tetrahydrofuran; for 6h; Heating;

DOI:10.1246/bcsj.77.1589

Reference yield: 55.0%

allyl methyl carbonate (35466-83-2) + 2-[4-(dimethylamino)phenyl]acetic acid (17078-28-3) → 1,2-bisethane (793-08-8) + 4-(but-3-enyl)-N,N-dimethylaniline (344408-47-5)

Guidance literature:

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; [Ir(ppy)₂(bpy)][BF₄]; In acetonitrile; at 25 ℃; for 2h; Irradiation; Inert atmosphere;

DOI:10.1021/ja508317j

Reference yield: 46.0%

4-dimethylamino phenylacetic acid allyl ester → 1,2-bisethane (793-08-8) + 4-(but-3-enyl)-N,N-dimethylaniline (344408-47-5)

Guidance literature:

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; [Ir(ppy)₂(bpy)][BF₄]; In acetonitrile; at 25 ℃; for 2h; Reagent/catalyst; Solvent; Irradiation; Inert atmosphere;

DOI:10.1021/ja508317j

upstream raw materials:

buta-1,3-diene

4-dimethylaminophenylmagnesium bromide

4-bromo-N,N-dimethylaniline

4-but-1-enylmagnesium bromide

Refernces

• 1、 Kanehara, Masayuki,Oumi, Yasunori,Sano, Tsuneji,Teranishi, Toshiharu. "Syntheses of the novel acidic and basic ligands and superlattice formation from gold nanoparticles through interparticle acid-base interaction". . p. 1589 - 1597. Retrieved 2007/10/03.