Diethyl trisulfide

Base Information

• Chemical Name: Diethyl trisulfide
• CAS No.: 3600-24-6
• Molecular Formula: C4H10 S3
• Molecular Weight: 154.321
• Hs Code.: 2930909090
• European Community (EC) Number: 222-754-1
• NSC Number: 97329
• UNII: 0JO6C5I84O
• DSSTox Substance ID: DTXSID3063097
• Nikkaji Number: J205.528G
• Wikidata: Q16070571
• Metabolomics Workbench ID: 48563
• Mol file: 3600-24-6.mol

Synonyms:Diethyl trisulfide;3,4,5-trithiaheptane;3600-24-6;Trisulfide, diethyl;Ethyl trisulfide;Diethyl trisulphide;(ethyltrisulfanyl)ethane;DIETHYLTRISULFANE;1,3-Diethyltrisulfane;NSC 97329;UNII-0JO6C5I84O;0JO6C5I84O;EINECS 222-754-1;NSC-97329;(ethyltrisulanyl)ethane;Ethyl trisulfide, 8CI;1,3-Diethyltrisulfane #;ethylsulfanyldisulfanylethane;SCHEMBL1358709;DTXSID3063097;FEMA NO. 4029;1- ETHYLTRISULFANYLETHANE;DIETHYL TRISULFIDE [FHFI];CHEBI:167087;NSC97329;MFCD00039906;FEMA NO. 4042, DIETHYL-;AKOS006271481;D5749;FT-0652815;EN300-7577184;Q16070571

Chemical Property of Diethyl trisulfide

Chemical Property:

• Vapor Pressure: 0.168mmHg at 25°C
• Melting Point: -72.6°C
• Refractive Index: 1.5590 (estimate)
• Boiling Point: 220.4°Cat760mmHg
• Flash Point: 87.3°C
• PSA: 75.90000
• Density: 1.13g/cm³
• LogP: 3.05580
• XLogP3: 2.1
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 4
• Exact Mass: 153.99446384
• Heavy Atom Count: 7
• Complexity: 26.1

Purity/Quality:

99% ^*data from raw suppliers

Diethyltrisulfane ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCSSSCC

Technology Process of Diethyl trisulfide

There total 51 articles about Diethyl trisulfide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 30.0%

ethyl iodide (75-03-6) → diethyltrisulfane (3600-24-6) + diethyltetrasulfane (13730-34-2)

Guidance literature:

With sulfur; potassium hydroxide; water; In tetrahydrofuran; for 2h; Ambient temperature;

DOI:10.1055/s-1980-29271

Reference yield:

ethyl bromide (74-96-4) → Diethyl disulfide (110-81-6) + diethyltrisulfane (3600-24-6) + diethyltetrasulfane (13730-34-2)

Guidance literature:

With potassium hydroxide; hydrazine hydrate; In water; at 50 - 70 ℃; for 0.5h;

Reference yield:

ethyl iodide (75-03-6) → Diethyl disulfide (110-81-6) + diethyltrisulfane (3600-24-6) + diethyltetrasulfane (13730-34-2)

Guidance literature:

With sodium hydroxide; hydrazine hydrate; In water; at 50 - 70 ℃; for 0.5h;

upstream raw materials:

ethyl bromide

diethyl pentasulfide

Ethanesulfenyl chloride

thioacetamide

Downstream raw materials:

thiophene

Thiophene-2-thiol

thieno[2,3-b]thiophene

thieno[3,2-b]thiophene

Refernces

• 1、 Milligan,B. et al.. "-". . p. 3608 - 3614. Retrieved 1963.
• 2、 Deryagina, E. N.,Grabelnykh, V. A.,Russavskaya, N. V.,Alekminskaya, O. V.. "New Routes to Poly(Alkylene Sulfidoselenides)". . p. 1729 - 1733. Retrieved 2007/10/03.
• 3、 Musorin,Sedunova,Trofimov. "Formation of dialkyl polysulfides from vinyl ethers in the system H2S-DMSO-MOH". . p. 794 - 797. Retrieved 2007/10/03.