4-(1H-Benzo[d][1,2,3]triazol-1-yl)aniline

Base Information

• Chemical Name: 4-(1H-Benzo[d][1,2,3]triazol-1-yl)aniline
• CAS No.: 78381-23-4
• Molecular Formula: C₁₂H₁₀N₄
• Molecular Weight: 210.238
• European Community (EC) Number: 864-462-2
• Nikkaji Number: J676.180A
• Mol file: 78381-23-4.mol

Synonyms:78381-23-4;4-(1H-1,2,3-benzotriazol-1-yl)aniline;4-(1H-Benzo[d][1,2,3]triazol-1-yl)aniline;4-(benzotriazol-1-yl)aniline;SCHEMBL4799345;MFCD01413444;AKOS005167782;EN300-231304;Z370714666

Chemical Property of 4-(1H-Benzo[d][1,2,3]triazol-1-yl)aniline

Chemical Property:

• XLogP3: 2.1
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 1
• Exact Mass: 210.090546336
• Heavy Atom Count: 16
• Complexity: 237

Purity/Quality:

4-(1H-Benzo[d][1,2,3]triazol-1-yl)aniline 97% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: C1=CC=C2C(=C1)N=NN2C3=CC=C(C=C3)N

Technology Process of 4-(1H-Benzo[d][1,2,3]triazol-1-yl)aniline

There total 6 articles about 4-(1H-Benzo[d][1,2,3]triazol-1-yl)aniline which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1-(4-nitrophenyl)-1H-benzo[d][1,2,3]triazole (4490-51-1) → 1-(4-aminophenyl)-1,2,3-benzotriazole (78381-23-4)

Guidance literature:

With tin(IV) chloride;

Reference yield:

4-<(4'-nitrophenyl)amino>aniline (56594-79-7) → 1-(4-aminophenyl)-1,2,3-benzotriazole (78381-23-4)

Guidance literature:

Multi-step reaction with 2 steps

1: glacial acetic acid, 4N sodium nitrite / ethanol / 0.5 h / 0 °C

2: stannic chloride

With tin(IV) chloride; acetic acid; sodium nitrite; In ethanol;

Reference yield:

1,2-diamino-benzene (95-54-5) → 1-(4-aminophenyl)-1,2,3-benzotriazole (78381-23-4)

Guidance literature:

Multi-step reaction with 3 steps

1: sodium acetate, copper / ethanol / 36 h / Heating

2: glacial acetic acid, 4N sodium nitrite / ethanol / 0.5 h / 0 °C

3: stannic chloride

With sodium acetate; tin(IV) chloride; copper; acetic acid; sodium nitrite; In ethanol;

upstream raw materials:

1-(4-nitrophenyl)-1H-benzo[d][1,2,3]triazole

4-<(4'-nitrophenyl)amino>aniline

1,2-diamino-benzene

para-nitrophenyl bromide

Downstream raw materials:

1-(4-benzotriazol-1-yl-anilino)-cyclopentanecarboxylic acid amide

1-(4-benzotriazol-1-yl-anilino)-cyclopentanecarbonitrile

Refernces

• 1、 Jankowski, Zdzislaw,Stolarski, Roland. "SYNTHESES AND PROPERTIES OF SOME DERIVATIVES OF N--NAPHTHALIMIDE". . p. 555 - 564. Retrieved 2007/10/02.