NICKELION

Base Information

• Chemical Name: NICKELION
• CAS No.: 14903-34-5
• Molecular Formula: Ni
• Molecular Weight: 58.69
• Mol file: 14903-34-5.mol

Synonyms:Ni1+;Nickel ion(1+); Nickel(1+); Nickel(1+) ion

Chemical Property of NICKELION

Chemical Property:

• PSA: 0.00000
• LogP: 0.00000

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of NICKELION

There total 18 articles about NICKELION which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

nickel(II) perchlorate + isopropyl alcohol (67-63-0,8013-70-5) → hydrogen (1333-74-0) + nickel(I)(1+) (14903-34-5)

Guidance literature:

With sodium dodecyl-sulfate; silver perchlorate; silver; In water; byproducts: (CH3)2COH, H2O; other Radiation; γ-irradiation ((60)Co source, 5.5E+4 rads/h) of AgClO4 and Ni(ClO4)2 soln. containing acetone and propanol-2 as sources of org. radicals and sodium dodecylsulfate as stabilizer of colloidal silver; UV spectroscopy; Kinetics;

Reference yield:

Ni(1+)*C2H5CH(CN)CH3=NiC2H5CH(CN)CH3(1+) → NiHCN(1+) + hydrogen (1333-74-0) + nickel(I)(1+) (14903-34-5)

Guidance literature:

In gas; byproducts: organic radicals and hydrocarbons; decompn. in MS; product distribution studied by MS;

DOI:10.1021/ja00158a019

Reference yield:

potassium tetracyanonickelate(II) → nickel (7440-02-0) + nickel(I)(1+) (14903-34-5)

Guidance literature:

With potassium chloride; In not given; Electrochem. Process; mercury jet electrode;

upstream raw materials:

oxonium

nickel

isopropyl alcohol

nickel(II)

Refernces

• 1、 Irion,Selinger. "FTMS studies of sputtered metal cluster ions. (II) The chemistry of Nin+ with C2H4 and CH4 at long timescales". . p. 1408 - 1412. Retrieved 1989.
• 2、 Kemper, Paul R.,Weis, Patrick,Bowers, Michael T.. "Ni+(H2)n: Ligand bond energies for ground state ions". . p. 503 - 510. Retrieved 1998.
• 3、 Fisher, Ellen R.,Armentrout, P. B.. "Reactions of Co+, Ni+, and Cu+ with Cyclopropane and Ethylene Oxide. Metal-Methylidene Ion Bond Energies". . p. 1674 - 1683. Retrieved 1990.